Preparation and structural properties of nonlinear optical borates K2(1−x)Rb2xAl2B2O7, 0 < x < 0.75

作者: B.G. Bazarov , T.A. Gavrilova , V.G. Grossman , M.S. Molokeev , Zh.G. Bazarova

DOI: 10.1016/J.JALLCOM.2011.11.115

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摘要: Abstract The structures of K2(1−x)Rb2xAl2B2O7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis X-ray powder diffraction data. solubility limit K2(1−x)Rb2xAl2B2O7 crystals has estimated as x ∼ 0.83–0.9. Nonlinear optical properties KRbAl2B2O7 verified by Kurtz–Perry method. Mechanisms structural parameter variation K2Al2B2O7 crystal family discussed.

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