An overview of Zn-catalyzed enantioselective aldol type C–C bond formation

作者: Amrutha P. Thankachan , S. Asha , K. S. Sindhu , Gopinathan Anilkumar

DOI: 10.1039/C5RA10102F

关键词:

摘要: Enantioselective aldol reactions are powerful tools for the creation of carbon–carbon bonds in a stereoselective manner. Several synthetic strategies have been developed asymmetric reactions; but among these, Zinc-catalyzed protocols enantioselective attained great significance due to its excellent functional group tolerance. Zinc catalysis has an undeniable over other catalytic systems non-toxic, easily available, cheap and environmentally benign properties. This review mainly focuses on aspects Zn-catalyzed type promoted by enolate chemistry.

参考文章(74)
Modern aldol reactions Wiley-VCH Verlag GmbH. ,(2004) , 10.1002/9783527619566
Zhijin Lu, Haibo Mei, Jianlin Han, Yi Pan, The mimic of type II aldolases chemistry: asymmetric synthesis of beta-hydroxy ketones by direct aldol reaction. Chemical Biology & Drug Design. ,vol. 76, pp. 181- 186 ,(2010) , 10.1111/J.1747-0285.2010.00998.X
Paul T. Anastas, John Charles Warner, Green Chemistry: Theory and Practice ,(1998)
Naoki Yoshikawa, Naoya Kumagai, Shigeki Matsunaga, Guido Moll, Takashi Ohshima, Takeyuki Suzuki, Masakatsu Shibasaki, Direct Catalytic Asymmetric Aldol Reaction:  Synthesis of Eithersyn- oranti-α,β-Dihydroxy Ketones Journal of the American Chemical Society. ,vol. 123, pp. 2466- 2467 ,(2001) , 10.1021/JA015580U
Barry M. Trost, Vince S. C. Yeh, Stereocontrolled Synthesis of (+)-Boronolide Organic Letters. ,vol. 4, pp. 3513- 3516 ,(2002) , 10.1021/OL026665I
Barry M. Trost, Cheyenne S. Brindle, The Direct Catalytic Asymmetric Aldol Reaction Chemical Society Reviews. ,vol. 39, pp. 1600- 1632 ,(2010) , 10.1039/B923537J
Barry M Trost, Cheyenne S Brindle, The Direct Catalytic Asymmetric Aldol Reaction European Journal of Organic Chemistry. ,vol. 2002, pp. 1595- 1601 ,(2002) , 10.1002/1099-0690(200205)2002:10<1595::AID-EJOC1595>3.0.CO;2-M
Jacek Mlynarski, Joanna Paradowska, Catalytic asymmetric aldol reactions in aqueous media Chemical Society Reviews. ,vol. 37, pp. 1502- 1511 ,(2008) , 10.1039/B710577K
Barry M. Trost, Jaray Jaratjaroonphong, Vichai Reutrakul, A Direct Catalytic Asymmetric Mannich-type Reaction via a Dinuclear Zinc Catalyst: Synthesis of Either anti- or syn-α-Hydroxy-β-Amino Ketones Journal of the American Chemical Society. ,vol. 128, pp. 2778- 2779 ,(2006) , 10.1021/JA057498V
Jacek Mlynarski, Sebastian Baś, Catalytic asymmetric aldol reactions in aqueous media – a 5 year update Chemical Society Reviews. ,vol. 43, pp. 577- 587 ,(2014) , 10.1039/C3CS60202H