Rational Design and Syntheses of Molecular Phase Transition Crystal Materials

摘要: Reversible phase transition materials (PTMs), of which their photoelectric responses can be modulated upon external heat, pressure, or light, have attracted great interest because the potential applications for electronic, optical, and energy-based devices. The design strategy chemical flexible structural components has feasibility to construct new PTMs with outstanding activities. Here, this paper presents our efforts on syntheses crystalline materials, as well related effects. These unique physical properties make them candidates switchable dielectrics, nonlinear optical switches, pyroelectric sensors, etc.