Using polymers to control substrate, ligand, or catalyst solubility

作者: David E. Bergbreiter

DOI: 10.1002/POLA.1212

关键词:

摘要: The attributes and design of soluble polymer supports for catalysis synthesis are discussed. By manipulating structure, can be prepared so that the solubility an attached reagent, substrate, or ligand is affected by heating, cooling, pH, solvent identity. Supports with such engineered useful both in organic catalysis. They used as purification handles a way to recover catalysts, turn reactions on off, more generally, handle separations.

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