NO2 disproportionation for the IR characterisation of basic zeolites

作者: Olivier Marie , Nicolas Malicki , Catherine Pommier , Pascale Massiani , Ann VosPostdoctoral Fellow of the Fund

DOI: 10.1039/B414664F

关键词:

摘要: NO2 disproportionation on alkaline zeolites is used to generate nitrosonium (NO+) and nitrate ions the surface, infrared vibrations observed are very sensitive cation chemical hardness basicity of zeolitic oxygen atoms.

参考文章(12)
Konstantin Hadjiivanov, V. Bushev, Margarita Kantcheva, Dimitar Klissurski, Infrared spectroscopy study of the species arising during nitrogen dioxide adsorption on titania (anatase) Langmuir. ,vol. 10, pp. 464- 471 ,(1994) , 10.1021/LA00014A021
R. Heidler, G. O. A. Janssens, W. J. Mortier, R. A. Schoonheydt, CHARGE SENSITIVITY ANALYSIS OF INTRINSIC BASICITY OF FAUJASITE-TYPE ZEOLITES USING THE ELECTRONEGATIVITY EQUALIZATION METHOD (EEM) The Journal of Physical Chemistry. ,vol. 100, pp. 19728- 19734 ,(1996) , 10.1021/JP9615619
W MORTIER, Zeolite electronegativity related to physicochemical properties Journal of Catalysis. ,vol. 55, pp. 138- 145 ,(1978) , 10.1016/0021-9517(78)90200-2
Carlos Henriques, Olivier Marie, Frédéric Thibault-Starzyk, Jean-Claude Lavalley, NO+ ions as IR probes for the location of OH groups and Na+ ions in main channels and side pockets of mordenite Microporous and Mesoporous Materials. ,vol. 50, pp. 167- 171 ,(2001) , 10.1016/S1387-1811(01)00444-9
Patricio Fuentealba, Heinzwerner Preuss, Hermann Stoll, László Von Szentpály, A proper account of core-polarization with pseudopotentials: single valence-electron alkali compounds Chemical Physics Letters. ,vol. 89, pp. 418- 422 ,(1982) , 10.1016/0009-2614(82)80012-2
Chien-Chung Chao, Jack H. Lunsford, Infrared studies of the disproportionation reaction of nitric oxide on Y-type zeolites Journal of the American Chemical Society. ,vol. 93, pp. 71- 77 ,(1971) , 10.1021/JA00730A013
DENISE BARTHOMEUF∗, Basic zeolites : Characterization and uses in adsorption and catalysis Catalysis Reviews-science and Engineering. ,vol. 38, pp. 521- 612 ,(1996) , 10.1080/01614949608006465
Chengteh Lee, Weitao Yang, Robert G. Parr, Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Physical Review B. ,vol. 37, pp. 785- 789 ,(1988) , 10.1103/PHYSREVB.37.785
Howard S. Sherry, The Ion-Exchange Properties of Zeolites. I. Univalent Ion Exchange in Synthetic Faujasite The Journal of Physical Chemistry. ,vol. 70, pp. 1158- 1168 ,(1966) , 10.1021/J100876A031
P. Geerlings, F. De Proft, W. Langenaeker, Conceptual density functional theory. Chemical Reviews. ,vol. 103, pp. 1793- 1873 ,(2003) , 10.1021/CR990029P