CuO Quantum Dots Embedded in Carbon Nanofibers as Binder-Free Anode for Sodium Ion Batteries with Enhanced Properties

作者: Xiaojun Wang , Yongchang Liu , Yijing Wang , Lifang Jiao

DOI: 10.1002/SMLL.201601474

关键词:

摘要: The design of sodium ion batteries is proposed based on the use flexible membrane composed ultrasmall transition metal oxides. In this paper, preparation CuO quantum dots (≈2 nm) delicately embedded in carbon nanofibers (denoted as 2-CuO@C) with a thin film via feasible electrospinning method reported. content can be controlled by altering synthetic conditions and optimized to 54 wt%. As binder-free anode for batteries, 2-CuO@C delivers an initial reversible capacity 528 mA h g-1 at current density 100 , exceptional rate capability 250 5000 ultra-stable 401 after 500 cycles . enhancement electrochemical performance attributed unique structure 2-CuO@C, which offers variety advantages: highly conductive matrix suppressing agglomeration grains, interconnected ensuring short transport length electrons, well-dispersed leading utilization rate, good mechanical properties resulting strong electrode integrity.

参考文章(41)
Wei-Jie Li, Shu-Lei Chou, Jia-Zhao Wang, Hua-Kun Liu, Shi-Xue Dou, Simply mixed commercial red phosphorus and carbon nanotube composite with exceptionally reversible sodium-ion storage Nano Letters. ,vol. 13, pp. 5480- 5484 ,(2013) , 10.1021/NL403053V
Kai He, Feng Lin, Yizhou Zhu, Xiqian Yu, Jing Li, Ruoqian Lin, Dennis Nordlund, Tsu-Chien Weng, Ryan M. Richards, Xiao-Qing Yang, Marca M. Doeff, Eric A. Stach, Yifei Mo, Huolin L. Xin, Dong Su, Sodiation Kinetics of Metal Oxide Conversion Electrodes: A Comparative Study with Lithiation. Nano Letters. ,vol. 15, pp. 5755- 5763 ,(2015) , 10.1021/ACS.NANOLETT.5B01709
Yonglong Shen, Meilan Guo, Xiaohong Xia, Guosheng Shao, Role of materials chemistry on the electrical/electronic properties of CuO thin films Acta Materialia. ,vol. 85, pp. 122- 131 ,(2015) , 10.1016/J.ACTAMAT.2014.11.018
Md Mokhlesur Rahman, Alexey M. Glushenkov, Thrinathreddy Ramireddy, Ying Chen, Electrochemical investigation of sodium reactivity with nanostructured Co3O4 for sodium-ion batteries Chemical Communications. ,vol. 50, pp. 5057- 5060 ,(2014) , 10.1039/C4CC01033G
Sara Abouali, Mohammad Akbari Garakani, Biao Zhang, Hui Luo, Zheng-Long Xu, Jian-Qiu Huang, Jiaqiang Huang, Jang-Kyo Kim, Co3O4/porous electrospun carbon nanofibers as anodes for high performance Li-ion batteries Journal of Materials Chemistry. ,vol. 2, pp. 16939- 16944 ,(2014) , 10.1039/C4TA03206C
Lijiang Wang, Kai Zhang, Zhe Hu, Wenchao Duan, Fangyi Cheng, Jun Chen, Porous CuO nanowires as the anode of rechargeable Na-ion batteries Nano Research. ,vol. 7, pp. 199- 208 ,(2014) , 10.1007/S12274-013-0387-6
Zelang Jian, Bin Zhao, Pan Liu, Fujun Li, Mingbo Zheng, Mingwei Chen, Yi Shi, Haoshen Zhou, Fe2O3 nanocrystals anchored onto graphene nanosheets as the anode material for low-cost sodium-ion batteries Chemical Communications. ,vol. 50, pp. 1215- 1217 ,(2014) , 10.1039/C3CC47977C
Franziska Klein, Birte Jache, Amrtha Bhide, Philipp Adelhelm, Conversion reactions for sodium-ion batteries Physical Chemistry Chemical Physics. ,vol. 15, pp. 15876- 15887 ,(2013) , 10.1039/C3CP52125G
Shujiang Ding, Jun Song Chen, Xiong Wen David Lou, One‐Dimensional Hierarchical Structures Composed of Novel Metal Oxide Nanosheets on a Carbon Nanotube Backbone and Their Lithium‐Storage Properties Advanced Functional Materials. ,vol. 21, pp. 4120- 4125 ,(2011) , 10.1002/ADFM.201100781
Yuxin Tang, Yanyan Zhang, Wenlong Li, Bing Ma, Xiaodong Chen, Rational material design for ultrafast rechargeable lithium-ion batteries Chemical Society Reviews. ,vol. 44, pp. 5926- 5940 ,(2015) , 10.1039/C4CS00442F