The H2S+ radical ion
作者： R.N. Dixon , G. Duxbury , M. Horani , J. Rostas
DOI: 10.1080/00268977100103311
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摘要: The emission spectrum between 4000 and 5000 A obtained by Horani, Leach Rostas controlled energy electron excitation of H2S is shown to belong H2S+. decrease subsequent increase the bending vibrational intervals in 2 1 state H2S+ D2S+ indicates a barrier linearity approximately 4600 cm-1. preliminary rotational analysis leads following molecular parameters for ground state: r 0″ = 1·358 A, valence angle 92° 54′. detailed comparison optical photoelectron spectra has been made selection rules are presented. It that order understand vibronic patterns both types it necessary consider detail Renner-Teller interaction. alone insufficient account interesting change 1-1 transition at energies corresponding potential maximum.
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