The Application of Buckingham π Theorem to Modeling Polypyrrole Synthesis done by Chemical Oxidative Polymerization

摘要: Buckingham π theorem was applied to model polypyrrole synthesis done by inverse emulsion polymerization route using Methanesulfonic acid as a dopant and potassium persulfate an oxidant. A list of independent parameters on which depends selected means functional relation between three dimensionless quantities; percent yield, conductivity temperature obtained. The actual form the function determined basis experimental analysis linear regression analysis. accuracy proposed application scrutinized synthesizing pristine salt said route. It corroborated from experiment that increase in yield directly proportional oxidant concentration. Conductivity high 3.77 S/cm obtained with maximum 94.54% at moderate range (293 K-298 K).