Synthesis of 3-aryl-1,2-dicarba-closo-dodecaboranes by Suzuki-Miyaura coupling reaction
作者： Yasuyuki Endo , Koei Aizawa , Kiminori Ohta
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摘要: In contrast to conventional syntheses of 3-aryl-o-carborane derivatives, which involve reconstruction the o-carborane cage or Pd-catalyzed coupling reaction 3-iodo-o-carborane with Grignard reagents, Suzuzki-Miyaura proceeds a variety aryl boronic acids, providing new route derivatives bearing easily transformable functional groups, including CH 3 O-, NO 2 -, CHO- and CN-. This approach provides easy access compounds scaffold.
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