Novel Intercalation Host System Based on Transition Metal (Fe2+, Co2+, Mn2+)−Chloranilate Coordination Polymers. Single Crystal Structures and Properties

摘要: The new iron(II), cobalt(II), and manganese(II) intercalation compounds {[M(CA)(H2O)2](G)}n (M = Fe2+, Co2+, Mn2+; H2CA chloranilic acid (C6H2O4Cl2); G H2O phenazine (C12H8N2; phz)) have been synthesized characterized. {[Fe(CA)(H2O)2](H2O)}n (1a) crystallizes in the monoclinic space group C2/c (No. 15) with a 4.914(2) A, b 14.222(2) c 13.987(2) β 94.98(2)°, V 973.8(4) A3, Z 4. {[Fe(CA)(H2O)2](phz)}n (2a) triclinic P1 2) 8.079(2) 11.366(3) 5.055(2) α 96.57(3)°, 98.70(3)°, γ 83.07(2)°, 453.3(3) 1. {[M(CA)(H2O)2](H2O)}n Co2+ (1b), Mn2+ (1c)) are isomorphous to 1a. For 1a−c, crystal structures consist of uncoordinated guest water molecules one-dimensional zigzag [M(CA)(H2O)2]k chains. Two occupying cis positions two chloranilate filling remaining sites bis bidentate fashion create octahedral environment around metal ion form chain (...