The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation.
作者： Dong-Ping Tao
DOI: 10.1038/SREP35792
关键词:
摘要: In a multi-component homogeneous system, the relationship between partial molar and quantity (RPMQ) is proved to be an equivalent relation of Gibbs-Duhem equation. The universal characteristics thermodynamic model conform equation are inferred from RPMQ. Based on inference, asymmetric regular solution suggested deal with those systems that exhibit strong negative deviation, positive both deviation ideality.
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