Graphitic Carbon Growth on MgO(100) by Molecular Beam Epitaxy

作者: S. K. Jerng , J. H. Lee , D. S. Yu , Y. S. Kim , Junga Ryou

DOI: 10.1021/JP210910U

关键词:

摘要: Direct graphene growth on insulating substrates is of great importance for electronics. Limited accomplishments by using molecular beam epitaxy have been demonstrated hexagonal symmetry. For comparison and further progress, we study the graphitic carbon cubic MgO substrates. Raman spectra clearly show D, G, 2D peaks, confirming formation nanocrystalline graphite. The degree graphitization comparable to those layers grown X-ray photoelectron spectroscopy proves dominance sp2 bonding, transmission electron microscopy reveals nanometer-scale clusters directly. flatness homogeneity MgO(100) are also beneficial potential applications heterostructures containing carbon. First-principles calculations elucidate that strong carbon–oxygen interaction limits in-plane coherence length.

参考文章(49)
A. C. Ferrari, J. Robertson, Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon Physical Review B. ,vol. 64, pp. 075414- ,(2001) , 10.1103/PHYSREVB.64.075414
I. V. Makarenko, A. N. Titkov, Z. Waqar, Ph. Dumas, E. V. Rut’kov, N. R. Gall’, Structural Properties of a Monolayer Graphite Film on the (111)Ir Surface Physics of the Solid State. ,vol. 49, pp. 371- 376 ,(2007) , 10.1134/S106378340702031X
Vimlesh Chandra, Jaesung Park, Young Chun, Jung Woo Lee, In-Chul Hwang, Kwang S. Kim, Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal ACS Nano. ,vol. 4, pp. 3979- 3986 ,(2010) , 10.1021/NN1008897
W. H. Wang, W. Han, K. Pi, K. M. McCreary, F. Miao, W. Bao, C. N. Lau, R. K. Kawakami, Growth of atomically smooth MgO films on graphene by molecular beam epitaxy Applied Physics Letters. ,vol. 93, pp. 183107- ,(2008) , 10.1063/1.3013820
Ying ying Wang, Zhen hua Ni, Ting Yu, Ze Xiang Shen, Hao min Wang, Yi hong Wu, Wei Chen, Andrew Thye Shen Wee, Raman Studies of Monolayer Graphene: The Substrate Effect Journal of Physical Chemistry C. ,vol. 112, pp. 10637- 10640 ,(2008) , 10.1021/JP8008404
Y.-M. Lin, C. Dimitrakopoulos, K. A. Jenkins, D. B. Farmer, H.-Y. Chiu, A. Grill, Ph. Avouris, 100-GHz Transistors from Wafer-Scale Epitaxial Graphene Science. ,vol. 327, pp. 662- 662 ,(2010) , 10.1126/SCIENCE.1184289
A. K. Geim, K. S. Novoselov, The rise of graphene Nature Materials. ,vol. 6, pp. 183- 191 ,(2007) , 10.1038/NMAT1849
L. G. Cançado, K. Takai, T. Enoki, M. Endo, Y. A. Kim, H. Mizusaki, A. Jorio, L. N. Coelho, R. Magalhães-Paniago, M. A. Pimenta, General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy Applied Physics Letters. ,vol. 88, pp. 163106- ,(2006) , 10.1063/1.2196057
Alexander A. Balandin, Irene Calizo, F. Miao, W. Bao, Graphene-on-Sapphire and Graphene-on-Glass: Raman Spectroscopy Study arXiv: Materials Science. ,(2007) , 10.1063/1.2805024
J. Hackley, D. Ali, J. DiPasquale, J. D. Demaree, C. J. K. Richardson, Graphitic carbon growth on Si(111) using solid source molecular beam epitaxy Applied Physics Letters. ,vol. 95, pp. 133114- ,(2009) , 10.1063/1.3242029