Assignments of autoionization states of O2
作者： C.Y. Robert Wu
DOI: 10.1016/0022-4073(87)90115-4
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摘要: Abstract Autoionization states of O2 leading to the b 4Σg-, B 2Σg- and c 4Σu- O+2 have been well established, while those a 4∏u A 2∏u are not certain. Further, some assignments autoionization determinations effective quantum numbers defects open questions. In view recent study isotopic oxygen molecules, vibrational for 2∏ucan be unamiguosly assigned. We systematically examined known Rydberg series suggested new interpretations several various O2+.
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