Molybdenum(0) and Tungsten(0) Complexes withP,SandP,SeMonooxidized Bis(phosphanyl)amine Ligands
作者： Harbi Tomah Al-Masri , Ziad Moussa , Atif Fazal , Mohammed Fettouhi
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摘要: Reactions of monooxidized thioyl and selenoyl bis(phosphanyl)amine ligands C10H7-1-N(P(E)Ph2)(PPh2) [E = S (1), Se (2)] with Mo(CO)4(pip)2 W(CO)4(cod) afforded the complexes [M(CO)4{1-κ2P,S}] [M Mo (3), W (4)] [M(CO)4{2-κ2P,Se}] (5), (6)]. Complexes 3–6 were characterized by multinuclear NMR (1H, 13C, 31P, 77Se NMR) IR spectroscopy. Crystal-structure determinations carried out on 3, 5, 6, which represent first examples structurally such group-6 metal carbonyls.
sci-hub.se 参考文章(40)
Francine Agbossou, Jean-François Carpentier, Frédéric Hapiot, Isabelle Suisse, André Mortreux, The aminophosphine-phosphinites and related ligands: synthesis, coordination chemistry and enantioselective catalysis1Dedicated to the memory of Professor Francis Petit1 Coordination Chemistry Reviews. ,vol. 178-180, pp. 1615- 1645 ,(1998) , 10.1016/S0010-8545(98)00088-5
Wilfred Louis Florio Armarego, Douglas Dalzell Perrin, D. R Perrin, Purification of laboratory chemicals ,(1966)
Harbi Tomah Al-Masri, Beshir M. Mohamed, Ziad Moussa, Mohamed H. Alkordi, Synthesis and Characterization of Carbonyl Group-6-Metal Derivatives with Ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N-naphthalen-1-yl-P,P-diphenylphosphinous Amide). Molecular Structure of cis-Tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C10H7-1-N(PPh2)2}]) Helvetica Chimica Acta. ,vol. 96, pp. 738- 746 ,(2013) , 10.1002/HLCA.201200315
Kirsty G Gaw, Martin B Smith, Jonathan W Steed, Facile syntheses of new multidentate (phosphino)amines: X-ray structure of 1,4-{(OC)4Mo(Ph2P)2NCH2}2C6H4 Journal of Organometallic Chemistry. ,vol. 664, pp. 294- 297 ,(2002) , 10.1016/S0022-328X(02)02025-9
Kirsty G. Gaw, Martin B. Smith, Alexandra M. Z. Slawin, Molybdenum(0), ruthenium(II), palladium(II), platinum(II), copper(I) and gold (I) complexes of a new methoxy functionalised bis(phosphino)amine: synthesis and structure New Journal of Chemistry. ,vol. 24, pp. 429- 435 ,(2000) , 10.1039/B001458N
Konstantin N Gavrilov, Aleksei I Polosukhin, Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium Russian Chemical Reviews. ,vol. 69, pp. 661- 682 ,(2000) , 10.1070/RC2000V069N08ABEH000559
Harbi Tomah Al-Masri, Joachim Sieler, Peter Lönnecke, Steffen Blaurock, Konstantin Domasevitch, Evamarie Hey-Hawkins, Synthesis and molecular structures of (2-dialkylaminophenyl)alcohols and of 2-phenylaminoalkyl-dimethylaminobenzene derivatives Tetrahedron. ,vol. 60, pp. 333- 339 ,(2004) , 10.1016/J.TET.2003.11.022
Harbi T. Al-Masri, Joachim Sieler, Peter Lönnecke, Peter C. Junk, Evamarie Hey-Hawkins, Synthesis, Characterization, and Crystal Structures of Novel Intramolecularly Base-Stabilized Borane Derivatives with Six- and Seven-Membered Chelate Rings Inorganic Chemistry. ,vol. 43, pp. 7162- 7169 ,(2004) , 10.1021/IC049352N
Harbi Tomah Al-Masri, Jens Baldamus, Evamarie Hey-Hawkins, Alcohol adducts of zinc dichloride: Molecular structure of [ZnCl2(THF){1-HOC(C6H11)2-2-NMe2C6H4}] Polyhedron. ,vol. 28, pp. 3515- 3518 ,(2009) , 10.1016/J.POLY.2009.07.049
Stephen M Aucott, Alexandra M.Z Slawin, J.Derek Woollins, Coordination chemistry of o-Ph2PNHC6H4P(S)Ph2 a P,S-donor ligand: synthesis of new Ru, Rh and Ir complexes Polyhedron. ,vol. 22, pp. 361- 368 ,(2003) , 10.1016/S0277-5387(02)01357-8