Organopolysiloxane-polyurea block copolymer release agents

作者: Leonard A. Tushaus , Gary T. Widerholt

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摘要: Block copolymers having a repeating unit comprised of polysiloxane and urea segments are prepared by copolymerizing certain diaminopolysiloxanes with diisocyanates. The invention also provides novel useful as precursors in the preparation block method making such diaminopolysiloxanes. Pressure-sensitive adhesive compositions comprising copolymer provided sheet materials coated same.

参考文章(15)
Christian Prud'Homme, Jacques Cavezzan, Organopolysiloxane/polyurethane elastomeric block copolymers ,(1982)
W. Noll, Chemie und Technologie der Silicone Verlag Chemie GMGH. ,(1960)
Frank A. Schurb, Jack L. Evans, Stratum having release properties and method of making ,(1973)
Ìskender YíIgör, Ahmad K. Sha'aban, Warren P. Steckle, Dinesh Tyagi, Garth L. Wilkes, James E. McGrath, Segmented organosiloxane copolymers. 1. Synthesis of siloxane—urea copolymers Polymer. ,vol. 25, pp. 1800- 1806 ,(1984) , 10.1016/0032-3861(84)90254-4
Yu Xue-Hai, M. R. Nagarajan, T. G. Grasel, P. E. Gibson, S. L. Cooper, Polydimethylsiloxane–polyurethane elastomers: Synthesis and properties of segmented copolymers and related zwitterionomers Journal of Polymer Science: Polymer Physics Edition. ,vol. 23, pp. 2319- 2338 ,(1985) , 10.1002/POL.1985.180231106
Charles M. Leir, William R. Bronn, Jerome J. Hoffman, Leonard A. Tushaus, Gary T. Wiederholt, Mieczyslaw H. Mazurek, Audrey A. Sherman, Block copolymer, method of making the same, diamine precursors of the same, method of making such diamines and end products comprising the block copolymer ,(1987)