The role of cations in the reduction of 9-fluorenone in bis(trifluoromethylsulfonyl)imide room temperature ionic liquids
作者： Irene Reche , Iluminada Gallardo , Gonzalo Guirado
DOI: 10.1039/C4NJ01200C
关键词:
摘要: A report is presented on some fundamental electrochemical studies based the effects of cations determination standard potential values for five bis(trifluoromethylsulfonyl)imide Room Temperature Ionic Liquids (RTILs) in reduction 9-fluorenone, a well-known redox probe. The obtained can be related to solvation process electrogenerated fluorenone radical anion. accurate above-mentioned RTILs, which are composed unsymmetrical organic and weakly-coordinating inorganic anion, used as good starting point establishing basis design new more environmentally friendly energetically efficient electrosynthetic routes, well optoelectronic devices chemistry those ionic solvents.
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