Nanostructures in Thermosetting Blends of Epoxy Resin with Polydimethylsiloxane-block-poly(ε-caprolactone)-block-polystyrene ABC Triblock Copolymer
作者： Wenchun Fan , Lei Wang , Sixun Zheng
DOI: 10.1021/MA8018014
关键词:
摘要: Polydimethylsiloxane-block-poly(e-caprolactone)-block-polystyrene ABC-type triblock copolymer (PDMS-b-PCL-b-PS) was synthesized via the sequential ring-opening polymerization and atom transfer radical polymerization. The ABC incorporated into epoxy to prepare nanostructured thermosets. In terms of difference in miscibility with subchains after before curing reaction, it is proposed that formation nanostructures follows combined mechanisms self-assembly reaction-induced microphase separation. self-organized nanophases could be formed reaction since PDMS polymer immiscible precursors reaction. separation PS occurred presence whereas PCL remain miscible By means atomic force microscopy ...
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S. Ritzenthaler, F. Court, L. David, E. Girard-Reydet, L. Leibler, J. P. Pascault, ABC Triblock Copolymers/Epoxy−Diamine Blends. 1. Keys To Achieve Nanostructured Thermosets Macromolecules. ,vol. 35, pp. 6245- 6254 ,(2002) , 10.1021/MA0121868
Yonathan S. Thio, Junxian Wu, Frank S. Bates, Epoxy toughening using low molecular weight poly(hexylene oxide)-poly(ethylene oxide) diblock copolymers Macromolecules. ,vol. 39, pp. 7187- 7189 ,(2006) , 10.1021/MA052731V
C. E. Hoppe, M. J. Galante, P. A. Oyanguren, R. J. J. Williams, E. Girard-Reydet, J. P. Pascault, Transparent multiphasic polystyrene/epoxy blends Polymer Engineering and Science. ,vol. 42, pp. 2361- 2368 ,(2002) , 10.1002/PEN.11122
Zhiguang Xu, Sixun Zheng, Reaction-Induced Microphase Separation in Epoxy Thermosets Containing Poly(∊-caprolactone)-block-poly(n-butyl acrylate) Diblock Copolymer Macromolecules. ,vol. 40, pp. 2548- 2558 ,(2007) , 10.1021/MA062486V
Valéry Rebizant, Volker Abetz, François Tournilhac, François Court, Ludwik Leibler, Reactive Tetrablock Copolymers Containing Glycidyl Methacrylate. Synthesis and Morphology Control in Epoxy−Amine Networks Macromolecules. ,vol. 36, pp. 9889- 9896 ,(2003) , 10.1021/MA0347565
Yuhong Hu, H. R. Motzer, A. M. Etxeberria, M. J. Fernandez-Berridi, J. J. Iruin, Paul C. Painter, Michael M. Coleman, Concerning the self-association ofN-vinyl pyrrolidone and its effect on the determination of equilibrium constants and the thermodynamics of mixing Macromolecular Chemistry and Physics. ,vol. 201, pp. 705- 714 ,(2000) , 10.1002/(SICI)1521-3935(20000301)201:6<705::AID-MACP705>3.0.CO;2-9
Robert B. Grubbs, Jennifer M. Dean, Margaret E. Broz, Frank S. Bates, Reactive Block Copolymers for Modification of Thermosetting Epoxy Macromolecules. ,vol. 33, pp. 9522- 9534 ,(2000) , 10.1021/MA001414F
Jennifer M. Dean, Robert B. Grubbs, Walid Saad, Robert F. Cook, Frank S. Bates, Mechanical properties of block copolymer vesicle and micelle modified epoxies Journal of Polymer Science Part B. ,vol. 41, pp. 2444- 2456 ,(2003) , 10.1002/POLB.10595
M COLEMAN, P PAINTER, Hydrogen bonded polymer blends Progress in Polymer Science. ,vol. 20, pp. 1- 59 ,(1995) , 10.1016/0079-6700(94)00038-4
Valéry Rebizant, Anne-Sophie Venet, François Tournilhac, Emmanuel Girard-Reydet, Christophe Navarro, Jean-Pierre Pascault, Ludwik Leibler, Chemistry and Mechanical Properties of Epoxy-Based Thermosets Reinforced by Reactive and Nonreactive SBMX Block Copolymers Macromolecules. ,vol. 37, pp. 8017- 8027 ,(2004) , 10.1021/MA0490754