Silver Composite Electrode for Voltammetric Determination of Halogenides

作者: S. Šebková , T. Navrátil , M. Kopanica

DOI: 10.1081/AL-120029739

关键词:

摘要: Abstract The application of the silver composite electrode prepared from silver, graphite powder and methacrylate resin for voltammetric determination halogenide ions was studied. Cathodic direct current (DC) as well differential pulse (DP) stripping voltammetry (DPV) enable chloride, bromide, iodide ions. achieved limits detection all determined are sufficient practical analytical purposes (tap water, natural etc.) results reported in this paper fully comparable with using other electrodes. possibilities sample analysis without elimination presence surface‐active substances or dissolved oxygen were represents a suitable sensor seems to be promising replacement mercury electrodes many cases.

参考文章(27)
Jan Krista, Miloslav Kopanica, Tome Navratil, Anodic stripping voltammetry for arsenic determination on composite gold electrode Chemia Analityczna. ,vol. 48, pp. 265- 272 ,(2003)
Jaroslav Heyrovský, Principles of polarography ,(1966)
G Colovos, GS Wilson, JL Moyers, None, Simultaneous determination of bromide and chloride by cathodic stripping voltammetry Analytical Chemistry. ,vol. 46, pp. 1051- 1054 ,(1974) , 10.1021/AC60344A027
Steven L. Petersen, Dennis E. Tallman, Silver composite electrode for voltammetry Analytical Chemistry. ,vol. 60, pp. 82- 86 ,(1988) , 10.1021/AC00152A020
Tomáš Navrátil, Světlana Šebková, Miloslav Kopanica, Voltammetry of lead cations on a new type of silver composite electrode in the presence of other cations. Analytical and Bioanalytical Chemistry. ,vol. 379, pp. 294- 301 ,(2004) , 10.1007/S00216-004-2517-1
Irving. Shain, S. P. Perone, Application of Stripping Analysis to the Determination of Iodide with Silver Microelectrodes Analytical Chemistry. ,vol. 33, pp. 325- 329 ,(1961) , 10.1021/AC60171A004
Bogdan Yosypchuk, Ladislav Novotný, Electrodes of Nontoxic Solid Amalgams for Electrochemical Measurements Electroanalysis. ,vol. 14, pp. 1733- 1738 ,(2002) , 10.1002/ELAN.200290018
Hong Shen, James E. Mark, Carl J. Seliskar, Harry B. Mark Jr., William R. Heineman, Stripping voltammetry of copper and lead using gold electrodes modified with self-assembled monolayers Journal of Solid State Electrochemistry. ,vol. 1, pp. 241- 247 ,(1997) , 10.1007/S100080050055