Solar-driven CO2 to CO reduction utilizing H2O as an electron donor by earth-abundant Mn-bipyridine complex and Ni-modified Fe-oxyhydroxide catalysts activated in a single-compartment reactor.
作者： Takeo Arai , Shunsuke Sato , Keita Sekizawa , Tomiko M. Suzuki , Takeshi Morikawa
DOI: 10.1039/C8CC07900E
关键词:
摘要: Photoelectrochemical CO2 to CO reduction was demonstrated with 3.4% solar-to-chemical conversion efficiency using polycrystalline silicon photovoltaic cells connected earth-abundant catalysts: a manganese complex polymer for and iron oxyhydroxide modified nickel compound water oxidation. The system operated around neutral pH in single-compartment reactor.
rsc.org
sci-hub.se 参考文章(24)
Takeo Arai, Shunsuke Sato, Takeshi Morikawa, A monolithic device for CO2 photoreduction to generate liquid organic substances in a single-compartment reactor Energy and Environmental Science. ,vol. 8, pp. 1998- 2002 ,(2015) , 10.1039/C5EE01314C
B. Beverskog, I. Puigdomenech, Revised Pourbaix diagrams for nickel at 25-300°C Corrosion Science. ,vol. 39, pp. 969- 980 ,(1997) , 10.1016/S0010-938X(97)00002-4
Jason A. Seabold, Kyoung-Shin Choi, Efficient and stable photo-oxidation of water by a bismuth vanadate photoanode coupled with an iron oxyhydroxide oxygen evolution catalyst. Journal of the American Chemical Society. ,vol. 134, pp. 2186- 2192 ,(2012) , 10.1021/JA209001D
K. Nagasubramanian, F.P. Chlanda, Kang-Jen Liu, Use of bipolar membranes for generation of acid and base — an engineering and economic analysis Journal of Membrane Science. ,vol. 2, pp. 109- 124 ,(1977) , 10.1016/S0376-7388(00)83237-8
Yoshitsune Sugano, Akihiko Ono, Ryota Kitagawa, Jun Tamura, Masakazu Yamagiwa, Yuki Kudo, Eishi Tsutsumi, Satoshi Mikoshiba, Crucial role of sustainable liquid junction potential for solar-to-carbon monoxide conversion by a photovoltaic photoelectrochemical system RSC Advances. ,vol. 5, pp. 54246- 54252 ,(2015) , 10.1039/C5RA07179H
William D. Chemelewski, Heung-Chan Lee, Jung-Fu Lin, Allen J. Bard, C. Buddie Mullins, Amorphous FeOOH Oxygen Evolution Reaction Catalyst for Photoelectrochemical Water Splitting Journal of the American Chemical Society. ,vol. 136, pp. 2843- 2850 ,(2014) , 10.1021/JA411835A
Bhupendra Kumar, Mark Llorente, Jesse Froehlich, Tram Dang, Aaron Sathrum, Clifford P. Kubiak, Photochemical and Photoelectrochemical Reduction of CO2 Annual Review of Physical Chemistry. ,vol. 63, pp. 541- 569 ,(2012) , 10.1146/ANNUREV-PHYSCHEM-032511-143759
Haining Tian, Molecular Catalyst Immobilized Photocathodes for Water/Proton and Carbon Dioxide Reduction Chemsuschem. ,vol. 8, pp. 3746- 3759 ,(2015) , 10.1002/CSSC.201500983
Mikaela Görlin, Manuel Gliech, Jorge Ferreira de Araújo, Sören Dresp, Arno Bergmann, Peter Strasser, Dynamical changes of a Ni-Fe oxide water splitting catalyst investigated at different pH Catalysis Today. ,vol. 262, pp. 65- 73 ,(2016) , 10.1016/J.CATTOD.2015.10.018
Oscar Diaz-Morales, David Ferrus-Suspedra, Marc T. M. Koper, The importance of nickel oxyhydroxide deprotonation on its activity towards electrochemical water oxidation Chemical Science. ,vol. 7, pp. 2639- 2645 ,(2016) , 10.1039/C5SC04486C