Metal-free organic dyes derived from triphenylethylene for dye-sensitized solar cells: tuning of the performance by phenothiazine and carbazole
作者： Chengjian Chen , Jin-Yun Liao , Zhenguo Chi , Bingjia Xu , Xiqi Zhang
DOI: 10.1039/C2JM30254C
关键词:
摘要: Four novel D–D–π–A configuration metal-free organic dyes (C3, P2, C2 and P3) with triphenylethylene phenothiazine moieties or carbazole as additional electron donors for dye-sensitized solar cells (DSSCs) have been synthesized. The based on C3, P3 efficiencies of 2.14%, 2.69%, 5.51% 6.55%, respectively, are obtained. cell exhibits the highest efficiency 6.55% accompanied by a short-circuit current density (Jsc) 12.18 mA cm−2, rather high open-circuit photovoltage (Voc) 826 mV, fill factor (ff) 0.65, performances which remarkable in DSSCs dyes. twisted non-planar decelerates charge recombination charge-separated state hence contributes to improvement performance DSSCs.
rsc.org
sci-hub.se 参考文章(48)
Gang Li, Ke-Jian Jiang, Ying-Feng Li, Shao-Lu Li, Lian-Ming Yang, Efficient structural modification of triphenylamine-based organic dyes for dye-sensitized solar cells Journal of Physical Chemistry C. ,vol. 112, pp. 11591- 11599 ,(2008) , 10.1021/JP802436V
Bing-Xin Lei, Wen-Jie Fang, Yuan-Fang Hou, Jin-Yun Liao, Dai-Bin Kuang, Cheng-Yong Su, All-solid-state electrolytes consisting of ionic liquid and carbon black for efficient dye-sensitized solar cells Journal of Photochemistry and Photobiology A-chemistry. ,vol. 216, pp. 8- 14 ,(2010) , 10.1016/J.JPHOTOCHEM.2010.08.023
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Hui Tong, Yongqiang Dong, Matthias Häußler, Yuning Hong, Jacky Wing Yip Lam, Herman H-Y. Sung, Ian D. Williams, Hoi Sing Kwok, Ben Zhong Tang, Molecular packing and aggregation-induced emission of 4-dicyanomethylene-2,6-distyryl-4H-pyran derivatives Chemical Physics Letters. ,vol. 428, pp. 326- 330 ,(2006) , 10.1016/J.CPLETT.2006.06.113
Gang Qian, Ze Zhong, Min Luo, Dengbin Yu, Zhiqiang Zhang, Dongge Ma, Zhi Yuan Wang, Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes Journal of Physical Chemistry C. ,vol. 113, pp. 1589- 1595 ,(2009) , 10.1021/JP809568A
Bingjia Xu, Zhenguo Chi, Jianyong Zhang, Xiqi Zhang, Haiyin Li, Xiaofang Li, Siwei Liu, Yi Zhang, Jiarui Xu, Piezofluorochromic and aggregation-induced-emission compounds containing triphenylethylene and tetraphenylethylene moieties. Chemistry-an Asian Journal. ,vol. 6, pp. 1470- 1478 ,(2011) , 10.1002/ASIA.201100211
Mohammad K. Nazeeruddin, Filippo De Angelis, Simona Fantacci, Annabella Selloni, Guido Viscardi, Paul Liska, Seigo Ito, Bessho Takeru, Michael Grätzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers Journal of the American Chemical Society. ,vol. 127, pp. 16835- 16847 ,(2005) , 10.1021/JA052467L
Kai Zhu, Nathan R. Neale, Alexander Miedaner, Arthur J. Frank, Enhanced Charge-Collection Efficiencies and Light Scattering in Dye-Sensitized Solar Cells Using Oriented TiO2 Nanotubes Arrays Nano Letters. ,vol. 7, pp. 69- 74 ,(2007) , 10.1021/NL062000O
Xiqi Zhang, Zhenguo Chi, Haiyin Li, Bingjia Xu, Xiaofang Li, Siwei Liu, Yi Zhang, Jiarui Xu, Synthesis and properties of novel aggregation-induced emission compounds with combined tetraphenylethylene and dicarbazolyl triphenylethylene moieties Journal of Materials Chemistry. ,vol. 21, pp. 1788- 1796 ,(2011) , 10.1039/C0JM02824J
Zhong-Sheng Wang, Nagatoshi Koumura, Yan Cui, Masabumi Takahashi, Hiroki Sekiguchi, Atsunori Mori, Toshitaka Kubo, Akihiro Furube, Kohjiro Hara, Hexylthiophene-Functionalized Carbazole Dyes for Efficient Molecular Photovoltaics: Tuning of Solar-Cell Performance by Structural Modification Chemistry of Materials. ,vol. 20, pp. 3993- 4003 ,(2008) , 10.1021/CM8003276