Hydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand.

作者： Xiang Xue , Xi-Sen Wang , Li-Zhong Wang , Ren-Gen Xiong , Brendan F. Abrahams

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摘要: The reaction of 4-cyanopyridine with NaN(3) in the presence H(2)O and a Lewis acid (CdCl(2)) affords novel 3D pillared-layered fluorescent phosphorescent coordination polymer Cd(3)(OH)(2)Cl(2)(4-PTZ)(2) (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while direct CdCl(2) H-PTZ gives simpler species Cd(4-PTZ)(2)(H(2)O)(2). solid-state structure nature 1 provide an indication type materials that may be formed as intermediates Sharpless-Demko for generation 5-substituted 1H-tetrazoles.