A Note Concerning l‐Type Doubling in Linear Polyatomic Molecules
作者： Harald H. Nielsen , Wave H. Shaffer
DOI: 10.1063/1.1723814
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摘要: It is shown that certain Coriolis interaction terms in the rotation‐vibration Hamiltonian of a linear polyatomic molecule give second‐order contributions to energy which remove degeneracy levels associated with quantum number l internal angular momentum arising from doubly degenerate perpendicular mode oscillation. This type splitting called ``l‐type doubling'' because it exactly like ``Λ‐type electronic diatomic molecules.
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sci-hub.se 参考文章(4)
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