Preparation and characterization of copper chloride supported on citric acid‐modified magnetite nanoparticles (Cu2+‐CA@Fe3O4) and evaluation of its catalytic activity in the reduction of nitroarene compounds

作者: Ehsan Ghonchepour , Elahe Yazdani , Dariush Saberi , Marzban Arefi , Akbar Heydari

DOI: 10.1002/AOC.3822

关键词:

摘要: A new, powerful and recyclable copper catalyst were prepared by heterogenization of chloride using Fe3O4 nano particles modified with citric acid as a linker. This system can catalyze reduction nitroaren compound to aniline derivatives in the presence Sodium borohydride agent moderate good yields. In addition, easy separation recoverable an external permanent magnet is dominant properties this (Cu2+-CA@Fe3O4).

参考文章(35)
V. H. Parker, Enzymic reduction of 2:4-dinitrophenol by rat-tissue homogenates Biochemical Journal. ,vol. 51, pp. 363- 370 ,(1952) , 10.1042/BJ0510363
Vladimir P Torchilin, Nanoparticulates as Drug Carriers Imperial College Press. ,(2006) , 10.1142/P432
Yi-Chun Kung, Sheng-Huei Hsiao, Fluorescent and electrochromic polyamides with pyrenylamine chromophore Journal of Materials Chemistry. ,vol. 20, pp. 5481- 5492 ,(2010) , 10.1039/C0JM00495B
N. Sarlak, M. Adeli, M. Karimi, M. Bordbare, M.A. Farahmandnejad, Quantitative study on the interaction of Ag+ and Pd2 + with CNT-graft-PCA (polycitric acid) in aqueous solution Journal of Molecular Liquids. ,vol. 180, pp. 39- 44 ,(2013) , 10.1016/J.MOLLIQ.2012.12.034
Alexander T. Shulgin, The six trimethoxyphenylisopropylamines (trimethoxyamphetamines). Journal of Medicinal Chemistry. ,vol. 9, pp. 445- 446 ,(1966) , 10.1021/JM00321A058
Weixi Zhang, Junyao Xie, Bin Rao, Meiming Luo, Iron-catalyzed N-arylsulfonamide formation through directly using nitroarenes as nitrogen sources. Journal of Organic Chemistry. ,vol. 80, pp. 3504- 3511 ,(2015) , 10.1021/ACS.JOC.5B00130
Bo Zhu, Tongxiang Fan, Di Zhang, Adsorption of copper ions from aqueous solution by citric acid modified soybean straw Journal of Hazardous Materials. ,vol. 153, pp. 300- 308 ,(2008) , 10.1016/J.JHAZMAT.2007.08.050
Hong-yu Li, Fang Li, Brendan Frett, Selective Reduction of Halogenated Nitroarenes with Hydrazine Hydrate in the Presence of Pd/C. Synlett. ,vol. 25, pp. 1403- 1408 ,(2014) , 10.1055/S-0033-1339025
Astha Shukla, Rajib Kumar Singha, Takehiko Sasaki, Rajaram Bal, Nanocrystalline Pt-CeO2 as an efficient catalyst for a room temperature selective reduction of nitroarenes Green Chemistry. ,vol. 17, pp. 785- 790 ,(2015) , 10.1039/C4GC01664E