Use of Homolytic Redox Processes in Organic Syntheses
作者： A. Citterio , R. Santi
DOI: 10.1007/978-94-009-0897-0_15
关键词:
摘要: The design of new radical stoichiometric redox reactions useful in the synthesis organic compounds is discussed taking examples inter and intramolecular oxidative alkylation aromatics reduc tive olefins promoted by metal salts. analysis fo-coused mainly on reactivity ∝-carbonylalkyl radicals generated Mn(III)acetate oxidation carbonyl or addition nucleophilic carbon free to ∝-enones. Efficient propagations terminations results good yield selectivity increase also efficiency initiation step.
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