Effects of electric current upon catalytic steam reforming of biomass gasification tar model compounds to syngas

作者: Jun Tao , Qiang Lu , Changqing Dong , Xiaoze Du , Erik Dahlquist

DOI: 10.1016/J.ENCONMAN.2015.05.003

关键词:

摘要: Abstract Electrochemical catalytic reforming (ECR) technique, known as electric current enhanced was proposed to convert the biomass gasification tar into syngas. In this study, Ni–CeO 2 /γ-Al O 3 catalyst prepared, and toluene employed major feedstock for ECR experiments using a fixed-bed lab-scale setup where thermal electrons could be generated provided catalyst. Several factors, including intensity, reaction temperature steam/carbon (S/C) ratio, were investigated reveal their effects on conversion of well composition gas products. Moreover, toluene, two other model compounds (benzene 1-methylnaphthalene) real (tar-containing wastewater) subjected long period stability tests. All used catalysts analyzed determine carbon contents. The results indicated that presence performance remarkably. reached 99.9% under 4 A, 800 °C S/C ratio 3. Stable performances benzene, 1-methylnaphthalene tar-containing wastewater also observed in process. H CO products, while CH 4 minor ones. Due promising capability, technique deserves further investigation application efficient conversion.

参考文章(35)
Daniel Duprez, Selective steam reforming of aromatic compounds on metal catalysts Applied Catalysis A: General. ,vol. 82, pp. 111- 157 ,(1992) , 10.1016/0926-860X(92)85001-R
Roberto Coll, Joan Salvadó, Xavier Farriol, Daniel Montané, Steam reforming model compounds of biomass gasification tars: conversion at different operating conditions and tendency towards coke formation Fuel Processing Technology. ,vol. 74, pp. 19- 31 ,(2001) , 10.1016/S0378-3820(01)00214-4
Bing-Shun Huang, Hsin-Yi Chen, Jia-Hong Kuo, Chu-Hsuan Chang, Ming-Yen Wey, Catalytic upgrading of syngas from fluidized bed air gasification of sawdust Bioresource Technology. ,vol. 110, pp. 670- 675 ,(2012) , 10.1016/J.BIORTECH.2012.01.098
Michael D. Brown, Eddie G. Baker, Lyle K. Mudge, Environmental design considerations for thermochemical biomass energy Biomass. ,vol. 11, pp. 255- 270 ,(1986) , 10.1016/0144-4565(86)90098-3
Linghong Zhang, Chunbao (Charles) Xu, Pascale Champagne, Overview of recent advances in thermo-chemical conversion of biomass. Energy Conversion and Management. ,vol. 51, pp. 969- 982 ,(2010) , 10.1016/J.ENCONMAN.2009.11.038
John N. Kuhn, Zhongkui Zhao, Larry G. Felix, Rachid B. Slimane, Chun W. Choi, Umit S. Ozkan, Olivine catalysts for methane- and tar-steam reforming Applied Catalysis B-environmental. ,vol. 81, pp. 14- 26 ,(2008) , 10.1016/J.APCATB.2007.11.040
Lixia Yuan, Yaqiong Chen, Chongfu Song, Tongqi Ye, Qingxiang Guo, Qingshi Zhu, Youshifumi Torimoto, Quanxin Li, Electrochemical catalytic reforming of oxygenated-organic compounds: a highly efficient method for production of hydrogen from bio-oil. Chemical Communications. pp. 5215- 5217 ,(2008) , 10.1039/B810851J
Jiang Li, Fan Huang, Lian Wang, Zhaoxiang Wang, Shuqin Yu, Youshifumi Torimoto, Masayoshi Sadakata, Quanxin Li, Mechanistic features for hydroxyl anion emission from the modified 12CaO.7Al2O3 surface. Journal of Physical Chemistry B. ,vol. 109, pp. 14599- 14603 ,(2005) , 10.1021/JP0517697
Sergio Rapagnà, Nader Jand, Pier Ugo Foscolo, Catalytic gasification of biomass to produce hydrogen rich gas International Journal of Hydrogen Energy. ,vol. 23, pp. 551- 557 ,(1998) , 10.1016/S0360-3199(97)00108-0
Thanh D.B. Nguyen, Son Ich Ngo, Young-Il Lim, Jeong Woo Lee, Uen-Do Lee, Byung-Ho Song, Three-stage steady-state model for biomass gasification in a dual circulating fluidized-bed Energy Conversion and Management. ,vol. 54, pp. 100- 112 ,(2012) , 10.1016/J.ENCONMAN.2011.09.019