CuInS2-Poly(3-(ethyl-4-butanoate)thiophene) nanocomposite solar cells: Preparation by an in situ formation route, performance and stability issues
作者： Eugen Maier , Thomas Rath , Wernfried Haas , Oliver Werzer , Robert Saf
DOI: 10.1016/J.SOLMAT.2010.12.025
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摘要: Abstract In this contribution we present an in situ method for the preparation of CuInS 2 –poly(3-(ethyl-4-butanoate)thiophene) (P3EBT) nanocomposite layers and their application solar cells. A precursor solution containing copper indium salts, thiourea conjugated polymer was prepared pyridine, which coated onto glass/ITO substrates followed by a heating step at 180 °C. The induced formation nanoparticles homogeneously dispersed matrix. investigated X-ray scattering techniques TEM methods showing that nano-scaled formed. By addition small amounts zinc salt to solution, (ZCIS) ZCIS–P3EBT active exhibited higher V OC than –P3EBT showed efficiencies about 0.4%. Additionally stability cells tested over time scale 172 h.
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sci-hub.se 参考文章(42)
E. Arici, H. Hoppe, F. Schäffler, D. Meissner, M.A. Malik, N.S. Sariciftci, Hybrid solar cells based on inorganic nanoclusters and conjugated polymers Thin Solid Films. pp. 612- 618 ,(2004) , 10.1016/J.TSF.2003.11.026
W.U. Huynh, J.J. Dittmer, W.C. Libby, G.L. Whiting, A.P. Alivisatos, Controlling the morphology of nanocrystal-polymer composites for solar cells Advanced Functional Materials. ,vol. 13, pp. 73- 79 ,(2003) , 10.1002/ADFM.200390009
J. Emerson-Reynolds, XXV.—On the synthesis of galena by means of thiocarbamide, and the deposition of lead sulphide as a specular film J. Chem. Soc., Trans.. ,vol. 45, pp. 162- 165 ,(1884) , 10.1039/CT8844500162
Brian R. Saunders, Michael L. Turner, Nanoparticle–polymer photovoltaic cells Advances in Colloid and Interface Science. ,vol. 138, pp. 1- 23 ,(2008) , 10.1016/J.CIS.2007.09.001
S.D. Mittleman, R. Singh, Electrical properties of cadmium and zinc doped CuInS2 Solid State Communications. ,vol. 22, pp. 659- 662 ,(1977) , 10.1016/0038-1098(77)90791-8
Barry C. Thompson, Jean M. J. Fréchet, Polymer–Fullerene Composite Solar Cells Angewandte Chemie. ,vol. 47, pp. 58- 77 ,(2008) , 10.1002/ANIE.200702506
M. Gruber, B.A. Stickler, G. Trimmel, F. Schürrer, K. Zojer, Impact of energy alignment and morphology on the efficiency in inorganic–organic hybrid solar cells Organic Electronics. ,vol. 11, pp. 1999- 2011 ,(2010) , 10.1016/J.ORGEL.2010.08.015
Peter M. Schaber, James Colson, Steven Higgins, Daniel Thielen, Bill Anspach, Jonathan Brauer, Thermal decomposition (pyrolysis) of urea in an open reaction vessel Thermochimica Acta. ,vol. 424, pp. 131- 142 ,(2004) , 10.1016/J.TCA.2004.05.018
H.J. Lewerenz, Development of copperindiumdisulfide into a solar material Solar Energy Materials and Solar Cells. ,vol. 83, pp. 395- 407 ,(2004) , 10.1016/J.SOLMAT.2004.02.034
Baoquan Sun, Henry J. Snaith, Anoop S. Dhoot, Sebastian Westenhoff, Neil C. Greenham, Vertically segregated hybrid blends for photovoltaic devices with improved efficiency Journal of Applied Physics. ,vol. 97, pp. 014914- ,(2005) , 10.1063/1.1804613