Organomanganese (II) reagents. XII: An efficient one-pot preparation of unsymmetrical secondary or tertiary alcohols
作者： G Cahiez , J Rivas-Enterrios , H Granger-Veyron
DOI: 10.1016/S0040-4039(00)84973-4
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摘要: Abstract Various unsymmetrical secondary or tertiary alcohols have been prepared in high yields by an efficient one-pot procedure involving the acylation of organomanganese reagent acyl chloride and addition to ketone formed various organometallic compounds (RLi, RmgX, LiAlH4, NaBH4. The complexation intermediate metallic salts present reaction mixture allows perform 1–2 step under exceptionally mild conditions (0 20°C).
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