A heteropentanuclear metal string complex [Mo2NiMo2(tpda)4(NCS)2] with two linearly aligned quadruply bonded Mo2 units connected by a Ni ion and a meso configuration of the complex

作者: Wei-Chieh Hung , Marc Sigrist , Shao-An Hua , Lai-Chin Wu , Tsai-Jung Liu

DOI: 10.1039/C6CC07364F

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摘要: A dimeric molybdenum precursor and nickel ions are used to synthesize a symmetric heteropentanuclear complex, [Mo2NiMo2(tpda)4(NCS)2]. This complex possesses unique structural features, as the four ligands coordinated metal framework in meso configuration. Furthermore, central Ni2+ ion is high spin state.

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