Electrochemical and spectroscopic characterization of poly (bithiophene + 2-methylfuran) copolymer
作者： Leila Lamiri , Belkacem Nessark , Farid Habelhames , Lakhdar Sibous
DOI: 10.1016/J.MOLSTRUC.2017.04.109
关键词:
摘要: Abstract In this work, Poly(bithiophene + 2-methylfuran) copolymer was successfully synthetized by an electrochemical polymerization of two monomers, bithiophene and 2-methylfuran in acetonitrile containing lithium perchlorate. The obtained characterized via cyclic voltammetry, impedance spectroscopy, UV–visible, scanning electron microscope, conductivity photocurrent measurements. voltammetry study showed redox couples characteristic Poly (bithiophene + 2-methylfuran) copolymer. spectroscopy revealed that the resistance film increases with addition 2-methylfuran. measurement good photoelectrochemical properties, making ideal candidate for photovoltaic cell applications.
harvard.edu
sci-hub.se 参考文章(44)
M.J. González‐Tejera, I. Carrillo, Cyclic voltammetric behaviour of polyfuran perchlorate doped films Journal of Applied Electrochemistry. ,vol. 32, pp. 447- 453 ,(2002) , 10.1023/A:1016381808539
Jin-Young Kim, Effect of halohydrocarbon solvents on the dielectric performance of a polymer film and its application to inorganic electroluminescent devices Materials Chemistry and Physics. ,vol. 162, pp. 162- 165 ,(2015) , 10.1016/J.MATCHEMPHYS.2015.05.052
Rui-rui Yue, Jing-kun Xu, Bao-yang Lu, Cong-cong Liu, Zhao-jin Zhu, Zhuo Zhang, Electrosyntheses and characterization of a fluorescent conducting copolymer of benzanthrone and thiophene Chinese Journal of Polymer Science. ,vol. 28, pp. 771- 780 ,(2010) , 10.1007/S10118-010-9141-7
Muzaffer Talu, Melike Kabasakaloḡlu, Fati Yıldırım, Bekir Sarı, Electrochemical synthesis and characterization of homopolymers of polyfuran and polythiophene and bipolymer films polyfuran/polythiophene and polythiophene/polyfuran Applied Surface Science. ,vol. 181, pp. 51- 60 ,(2001) , 10.1016/S0169-4332(01)00355-5
P. Morvillo, F. Parenti, R. Diana, C. Fontanesi, A. Mucci, F. Tassinari, L. Schenetti, A novel copolymer from benzodithiophene and alkylsulfanyl-bithiophene: Synthesis, characterization and application in polymer solar cells Solar Energy Materials and Solar Cells. ,vol. 104, pp. 45- 52 ,(2012) , 10.1016/J.SOLMAT.2012.04.044
Shijie Zhen, Jingkun Xu, Baoyang Lu, Shimin Zhang, Li Zhao, Jie Li, Tuning the optoelectronic properties of polyfuran by design of furan-EDOT monomers and free-standing films with enhanced redox stability and electrochromic performances Electrochimica Acta. ,vol. 146, pp. 666- 678 ,(2014) , 10.1016/J.ELECTACTA.2014.09.034
Fadi Alakhras, Rudolf Holze, In situ UV–vis- and FT-IR-spectroscopy of electrochemically synthesized furan–thiophene copolymers Synthetic Metals. ,vol. 157, pp. 109- 119 ,(2007) , 10.1016/J.SYNTHMET.2006.12.011
Martin Helgesen, Roar Søndergaard, Frederik C. Krebs, Advanced materials and processes for polymer solar cell devices J. Mater. Chem.. ,vol. 20, pp. 36- 60 ,(2010) , 10.1039/B913168J
Belkıs Ustamehmetoglu, Fatma Demir, Esma Sezer, Electrochemical copolymerization of benzothiophene with thiophene Progress in Organic Coatings. ,vol. 76, pp. 1515- 1521 ,(2013) , 10.1016/J.PORGCOAT.2012.07.016
Teketel Yohannes, J.C. Carlberg, O. Inganäs, Theodros Solomon, Electrochemical and spectroscopic characteristics of copolymers electrochemically synthesized from 3-methylthiophene and 3,4-ethylenedioxy thiophene Synthetic Metals. ,vol. 88, pp. 15- 21 ,(1997) , 10.1016/S0379-6779(97)80878-8