Adsorption properties of pyridylphenylene dendrimers
作者： Olga Serenko , Pavel Strashnov , Gennadiy Kapustin , Mikhail Kalinin , Nina Kuchkina
DOI: 10.1039/C6RA27064F
关键词:
摘要: Here we report a sorption and surface properties study of the first three generations polypyridylphenylene dendrimers. A BET analysis N2 adsorption/desorption isotherms at 77 K yielded specific area values not exceeding 100 m2 g−1, while theoretical estimates predicted large pore volumes areas thousands square meters per gram. By means MD simulations, showed this difference to be due close packing dendrimers in bulk. T-plot BJH analyses revealed mesoporous character studied systems, with sizes comparable diameters individual dendrimer molecules. The measured water vapor on 1 3 implied chemisorption process involving formation hydrogen bonds.
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sci-hub.se 参考文章(33)
V. V. Ugrozov, A. N. Filippov, Yu. I. Sidorenko, Theoretical Description of the Hygroscopicity of Hydrophilic Biopolymers and Their Mixtures Colloid Journal. ,vol. 69, pp. 232- 236 ,(2007) , 10.1134/S1061933X07020135
Ekaterina V. Andreitchenko, Christopher G. Clark, Roland E. Bauer, Günter Lieser, Klaus Müllen, Pushing the Synthetic Limit: Polyphenylene Dendrimers with “Exploded” Branching Units—22-nm-Diameter, Monodisperse, Stiff Macromolecules Angewandte Chemie International Edition. ,vol. 44, pp. 6348- 6354 ,(2005) , 10.1002/ANIE.200501368
David Türp, Thi-Thanh-Tam Nguyen, Martin Baumgarten, Klaus Müllen, Uniquely versatile: nano-site defined materials based on polyphenylene dendrimers New Journal of Chemistry. ,vol. 36, pp. 282- 298 ,(2012) , 10.1039/C1NJ20449A
Yun Li, Jiajia Yang, Chaonan Huang, Longxing Wang, Jincheng Wang, Jiping Chen, Dendrimer-functionalized mesoporous silica as a reversed-phase/anion-exchange mixed-mode sorbent for solid phase extraction of acid drugs in human urine. Journal of Chromatography A. ,vol. 1392, pp. 28- 36 ,(2015) , 10.1016/J.CHROMA.2015.03.003
M S Rajadurai, Zinaida B Shifrina, N V Kuchkina, Aleksandr L Rusanov, K Müllen, Rigid aromatic dendrimers Russian Chemical Reviews. ,vol. 76, pp. 767- 783 ,(2007) , 10.1070/RC2007V076N08ABEH003671
Bandar Fadhel, Milton Hearn, Alan Chaffee, CO2 adsorption by PAMAM dendrimers: Significant effect of impregnation into SBA-15 Microporous and Mesoporous Materials. ,vol. 123, pp. 140- 149 ,(2009) , 10.1016/J.MICROMESO.2009.03.040
Gregory S. Larsen, Ping Lin, Kyle E. Hart, Coray M. Colina, Molecular Simulations of PIM-1-like Polymers of Intrinsic Microporosity Macromolecules. ,vol. 44, pp. 6944- 6951 ,(2011) , 10.1021/MA200345V
Yu Jing, Li Wei, Yundong Wang, Yanmei Yu, Synthesis, characterization and CO2 capture of mesoporous SBA-15 adsorbents functionalized with melamine-based and acrylate-based amine dendrimers Microporous and Mesoporous Materials. ,vol. 183, pp. 124- 133 ,(2014) , 10.1016/J.MICROMESO.2013.09.008
Blanca González, Montserrat Colilla, Carlos López de Laorden, María Vallet-Regí, A novel synthetic strategy for covalently bonding dendrimers to ordered mesoporous silica: potential drug delivery applications Journal of Materials Chemistry. ,vol. 19, pp. 9012- 9024 ,(2009) , 10.1039/B915331D
Malte Brutschy, René Stangenberg, Cornelia Beer, Daniel Lubczyk, Martin Baumgarten, Klaus Müllen, Siegfried R. Waldvogel, The Generation Effect: Cavity Accessibility in Dense-Shell Polyphenylene Dendrimers ChemPlusChem. ,vol. 80, pp. 54- 56 ,(2015) , 10.1002/CPLU.201402298