Oxidations of Organic Compounds with Osmium Tetroxide
作者： Hari Shankar Singh
DOI: 10.1007/978-1-4613-2109-5_12
关键词:
摘要: Metal compounds like potassium permanganate, hexacyanoferrate(III), ruthenium tetroxide, and osmium tetroxide are widely employed as oxidants in an alkaline medium. Apart from synthetic applications the laboratory these also important industrial syntheses. Osmium is oldest compound has been generally used for hydroxylation of olefins. Ruthenium reacts same way a vigorous oxidant even under mild conditions.
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sci-hub.st 参考文章(190)
K Burton, Oxidation of pyrimidine nucleosides and nucleotides by osmium tetroxide Biochemical Journal. ,vol. 104, pp. 686- 694 ,(1967) , 10.1042/BJ1040686
MP Singh, SINGH HS, SINGH BN, Narendra Singh, Madhir Kumar, None, Kinetik und Mechanismus der durch Osmiumtetroxid katalysierten Oxidation von Cyclohexanol und Methylcyclohexanol durch alkalische Hexacyanoferrat(III)-ionen Monatshefte Fur Chemie. ,vol. 109, pp. 1373- 1382 ,(1978) , 10.1007/BF00906050
Kenneth B. Wiberg, Walter S. Trahanovsky, Oxidation in organic chemistry Academic Press. ,(1982)
Herbert O. House, Modern Synthetic Reactions ,(1972)
Tokuo Kubota, Keiji Yoshida, Fumihiko Watanabe, The Configuration of the Products obtained from Hydroxylation of Steroidal Δ1, 4-3-Ketones with Osmium Tetroxide Chemical & Pharmaceutical Bulletin. ,vol. 14, pp. 1426- 1430 ,(1966) , 10.1248/CPB.14.1426
A. Banaszek, A. Zamojski, Derivatives of 2-alkoxy-5,6-dihydro-2h-pyran as starting materials in the synthesis of monosaccharides Carbohydrate Research. ,vol. 25, pp. 453- 463 ,(1972) , 10.1016/S0008-6215(00)81657-2
Kay Tanaka, On the Mode of Action of Hypoglycin A Journal of Biological Chemistry. ,vol. 247, pp. 7465- 7478 ,(1972) , 10.1016/S0021-9258(19)44549-3
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
Tokuo Kubota, Fumiko Hayashi, Studies on a-norsteroids—VI : Directing effects of the C11-substituents on the addition of osmium tetroxide to steroidal Δ1,4-3-ketones Tetrahedron. ,vol. 23, pp. 995- 1006 ,(1967) , 10.1016/0040-4020(67)85047-6
G.F. Bahr, Osmium tetroxide and ruthenium tetroxide and their reactions with biologically important substances Experimental Cell Research. ,vol. 7, pp. 457- 479 ,(1954) , 10.1016/S0014-4827(54)80091-7