Series of novel 3D microporous heterometallic 3d–4f coordination frameworks with (5,6)-connected topology: synthesis, crystal structure and magnetic properties
作者： ChuJun Chen , Ning Wang , Yi Long , JinYing Gao , WeiPing Xie
DOI: 10.1039/C3CE40346G
关键词:
摘要: The hydrothermal reaction of rare earth nitrates, CuCN, 1H-1,2,3-triazole-4,5-dicarboxylic acid (H3tda), and isonicotinic (Hina) resulted in the formation a new series 3d–4f heterometallic coordination polymers [LnCu(tda)(ina)2(H2O)]·3H2O (Ln = Eu (1), Tb (2), Gd (3), Dy (4), Ho (5)], H3tda acid, Hina acid). Complexes 1–5 are isostructural structurally characterized by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis (TGA), single-crystal powder X-ray diffraction (PXRD). Single-crystal reveals that metal cations these compounds firstly interconnected ligands to produce carpet-shaped ring [Ln2(tda)2Cu4], then pillared bridging molecules form 3D layer-pillared porous Ln(III)–Cu(II) polymers. In addition, magnetic properties were also investigated detail.
rsc.org
sci-hub.se 参考文章(39)
Junji Inanaga, Hiroshi Furuno, Tetsuji Hayano, Asymmetric catalysis and amplification with chiral lanthanide complexes. Chemical Reviews. ,vol. 102, pp. 2211- 2225 ,(2002) , 10.1021/CR010444T
Jean-Claude G. Bünzli, Claude Piguet, Lanthanide-containing molecular and supramolecular polymetallic functional assemblies. Chemical Reviews. ,vol. 102, pp. 1897- 1928 ,(2002) , 10.1021/CR010299J
You-Gui Huang, Min-Yan Wu, Wei Wei, Qiang Gao, Da-Qiang Yuan, Fei-Long Jiang, Mao-Chun Hong, Unprecedented ferromagnetic interaction in an erbium(III)–copper(II) coordination polymer Journal of Molecular Structure. ,vol. 885, pp. 23- 27 ,(2008) , 10.1016/J.MOLSTRUC.2007.10.002
Yi-Shan Song, Bing Yan, Lin-Hong Weng, Synthesis and crystal structure of a novel two-dimensional 3d–4f heterometallic coordination polymer constructed from three-ply-like layers Inorganic Chemistry Communications. ,vol. 9, pp. 567- 570 ,(2006) , 10.1016/J.INOCHE.2006.02.028
Maria G. F. Vaz, Luiza M. M. Pinheiro, H. O. Stumpf, Antônio F. C. Alcântara, Stéphane Golhen, Lahcène Ouahab, Olivier Cador, Corine Mathonière, Olivier Kahn, Soft and Hard Molecule-Based Magnets of Formula [(Etrad)2M2{Cu(opba)}3]⋅S [Etrad+=Radical Cation, MII=MnII or CoII, opba=Ortho-phenylenebis(oxamato), S=Solvent Molecules], with a Fully Interlocked Structure Chemistry - A European Journal. ,vol. 5, pp. 1486- 1495 ,(1999) , 10.1002/(SICI)1521-3765(19990503)5:5<1486::AID-CHEM1486>3.0.CO;2-F
Zhao-Yang Li, Jing-Wei Dai, Shan-Tang Yue, Ying-Liang Liu, Novel three-dimensional Ln–Ag 4d–4f heteropentametallic helix-based microporous metal–organic framework with unprecedented (3,4,5,6)-connected topology constructed from isonicotinate ligand CrystEngComm. ,vol. 12, pp. 2014- 2017 ,(2010) , 10.1039/C000058B
Xin Hu, Yong-Fei Zeng, Zhuo Chen, EC Sanudo, Fu-Chen Liu, J Ribas, Xian-He Bu, None, 3d−4f Coordination Polymers Containing Alternating EE/EO Azido Chain Synthesized by Synergistic Coordination of Lanthanide and Transition Metal Ions Crystal Growth & Design. ,vol. 9, pp. 421- 426 ,(2009) , 10.1021/CG8006475
Ying-Ying Bai, Yan Huang, Bing Yan, Yi-Shan Song, Lin-Hong Weng, A novel three-dimensional 3d–4f heterometallic coordination polymer: Crystal structure and photoluminescence Inorganic Chemistry Communications. ,vol. 11, pp. 1030- 1032 ,(2008) , 10.1016/J.INOCHE.2008.05.002
Rajesh Koner, Gene-Hsiang Lee, Yu Wang, Ho-Hsiang Wei, Sasankasekhar Mohanta, Two New Diphenoxo-Bridged Discrete Dinuclear CuIIGdIII Compounds with Cyclic Diimino Moieties: Syntheses, Structures, and Magnetic Properties European Journal of Inorganic Chemistry. ,vol. 2005, pp. 1500- 1505 ,(2005) , 10.1002/EJIC.200400858
Yue Ma, Gong-Feng Xu, Xi Yang, Li-Cun Li, Jinkui Tang, Shi-Ping Yan, Peng Cheng, Dai-Zheng Liao, Pyrazine-bridged Dy2 single-molecule magnet with a large anisotropic barrier. Chemical Communications. ,vol. 46, pp. 8264- 8266 ,(2010) , 10.1039/C0CC01423K