Miscibility studies of PVC/Aramid blends

作者: Saima Shabbir , Sonia Zulfiqar , Muhammad Ishaq , Muhammad Ilyas Sarwar

DOI: 10.1007/S00396-007-1811-9

关键词:

摘要: Blends containing PVC and aramid (Ar) matrices were probed for their miscibility. In this respect, Ar chains synthesized by aromatic diamine diacid chloride in amide solvent. The thus was characterized through Fourier transform infrared (FTIR) spectroscopy molecular weight determination. Blend system Ar/PVC investigated over a range of ratios. Their mechanical profiles terms maximum stress, strain, toughness, initial moduli have been explored. Thermal properties morphology the blends estimated using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), electron microscopy (SEM). A good correlation observed between thermal, mechanical, morphological blends. presence hydrogen bonding among polymers evaluated FTIR spectroscopy, which is believed to be responsible blend Optimal thermal depicted 40-wt% matrix.

参考文章(35)
Lloyd M. Robeson, Olagoke Olabisi, Montgomery T. Shaw, Polymer-polymer miscibility ,(1979)
Marino Xanthos, Polymers and Polymer Composites John Wiley & Sons, Ltd. pp. 1- 16 ,(2005) , 10.1002/9783527629848.CH1
G. Talamini, G. Pezzin, Kinetic study on the reaction of polyvinyl chloride thermal dehydrochlorination Macromolecular Chemistry and Physics. ,vol. 39, pp. 26- 38 ,(1960) , 10.1002/MACP.1960.020390103
R. Asaletha, M.G. Kumaran, Sabu Thomas, Thermal behaviour of natural rubber/polystyrene blends: thermogravimetric and differential scanning calorimetric analysis Polymer Degradation and Stability. ,vol. 61, pp. 431- 439 ,(1998) , 10.1016/S0141-3910(97)00229-2
A. Crosato-Arnaldi, G. Palma, E. Peggion, G. Talamini, Investigations on thermal dehydrochlorination of poly(vinyl chloride) Journal of Applied Polymer Science. ,vol. 8, pp. 747- 754 ,(1964) , 10.1002/APP.1964.070080215
G. Pezzin, G. Ajroldi, C. Garbuglio, Dynamic-mechanical study of the secondary transition of poly(vinyl chloride) Journal of Applied Polymer Science. ,vol. 11, pp. 2553- 2566 ,(1967) , 10.1002/APP.1967.070111215
C. Lavallée, M. Carmel, L. A. Utracki, J. P. Szabo, I. A. Keough, B. D. Favis, Thermal and viscoelastic behavior of polyurethane/polyvinylchloride blends Polymer Engineering and Science. ,vol. 32, pp. 1716- 1726 ,(1992) , 10.1002/PEN.760322210