Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds
作者： Ramesh Giri , Jin-Quan Yu
DOI: 10.1021/JA8063827
关键词:
摘要: A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The conditions are also applicable vinyl C−H bonds. first insertion Pd−aryl complex from carboxylic characterized by X-ray crystallography.
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