Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

作者: Douglas W. Stephan

DOI: 10.1039/B819621D

关键词:

摘要: The combination of Lewis acids and bases that are sterically precluded from forming acid–base adducts, termed Frustrated pairs provide a unique route to the activation small molecules applications in catalysis.

参考文章(49)
R. Noyori, M. Kitamura, T. Ohkuma, Toward efficient asymmetric hydrogenation: Architectural and functional engineering of chiral molecular catalysts Proceedings of the National Academy of Sciences of the United States of America. ,vol. 101, pp. 5356- 5362 ,(2004) , 10.1073/PNAS.0307928100
Lourdes Cabrera, Gregory C. Welch, Jason D. Masuda, Pingrong Wei, Douglas W. Stephan, Pyridine and phosphine reactions with [CPh3][B(C6F5)4] Inorganica Chimica Acta. ,vol. 359, pp. 3066- 3071 ,(2006) , 10.1016/J.ICA.2006.02.006
Patrick Spies, Gerhard Erker, Gerald Kehr, Klaus Bergander, Roland Fröhlich, Stefan Grimme, Douglas W. Stephan, Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct. Chemical Communications. pp. 5072- 5074 ,(2007) , 10.1039/B710475H
Georg Wittig, Alfred Rückert, Über Komplexbildung mit Triphenylbor (II. Mitt.) European Journal of Organic Chemistry. ,vol. 566, pp. 101- 113 ,(1950) , 10.1002/JLAC.19505660202
Gregory C. Welch, Jason D. Masuda, Douglas W. Stephan, Phosphonium-borate zwitterions, anionic phosphines, and dianionic phosphonium-dialkoxides via tetrahydrofuran ring-opening reactions. Inorganic Chemistry. ,vol. 45, pp. 478- 480 ,(2006) , 10.1021/IC051713R
Daniel J. Parks, Warren E. Piers, Glenn P. A. Yap, Synthesis, Properties, and Hydroboration Activity of the Highly Electrophilic Borane Bis(pentafluorophenyl)borane, HB(C6F5)21 Organometallics. ,vol. 17, pp. 5492- 5503 ,(1998) , 10.1021/OM980673E
Alberto Ramos, Alan J. Lough, Douglas W. Stephan, Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3 Chemical Communications. pp. 1118- 1120 ,(2009) , 10.1039/B819525K
Gregory C. Welch, Lourdes Cabrera, Preston A. Chase, Emily Hollink, Jason D. Masuda, Pingrong Wei, Douglas W. Stephan, Tuning Lewis acidity using the reactivity of “frustrated Lewis pairs”: facile formation of phosphine-boranes and cationic phosphonium-boranes Dalton Transactions. pp. 3407- 3414 ,(2007) , 10.1039/B704417H
Charles P. Casey, Galina A. Bikzhanova, Ilia A. Guzei, Stereochemistry of imine reduction by a hydroxycyclopentadienyl ruthenium hydride. Journal of the American Chemical Society. ,vol. 128, pp. 2286- 2293 ,(2006) , 10.1021/JA056402U