Multishelled Co3O4-Fe3O4 hollow spheres with even magnetic phase distribution: Synthesis, magnetic properties and their application in water treatment

作者: Xi Wang , Yeteng Zhong , Tianyou Zhai , Yanfeng Guo , Shimou Chen

DOI: 10.1039/C1JM13180J

关键词:

摘要: Nowadays, despite the success evidenced in synthesis of hybrid materials, spherical materials are usually based on core-shell structures or alloy-like ensembles with homogenous distribution all components. For core-shells, performance a core part is hampered due to thick shell, and commonly have low surface area. Therefore, multishelled hollow both even phase well-ordered building blocks, may be better choice. In this paper, we developed new method successfully fabricate Co3O4-Fe3O4 above ideal structure. As-prepared products definite structural advantages. these not only exhibit excellent ability waste-water treatment applications, but also feasible for fast recyclable via simple magnetic separation. addition, they show interesting structure-dependent properties could serve as model material heterogeneous antiferromagnet/ferromagnet system without clear/sharp interfaces. Needless say, our newly synthetic approach extended toward other functional distribution.

参考文章(40)
M. Sohma, K. Kawaguchi, T. Manago, Strain-induced magnetic anisotropy in epitaxial Fe3O4/Co3O4 multilayers Journal of Applied Physics. ,vol. 89, pp. 2843- 2846 ,(2001) , 10.1063/1.1337591
Yonghui Deng, Dawei Qi, Chunhui Deng, Xiangmin Zhang, Dongyuan Zhao, Superparamagnetic High-Magnetization Microspheres with an Fe3O4@SiO2 Core and Perpendicularly Aligned Mesoporous SiO2 Shell for Removal of Microcystins Journal of the American Chemical Society. ,vol. 130, pp. 28- 29 ,(2008) , 10.1021/JA0777584
Jinping Liu, Jian Jiang, Chuanwei Cheng, Hongxing Li, Jixuan Zhang, Hao Gong, Hong Jin Fan, Co3O4 Nanowire@MnO2 Ultrathin Nanosheet Core/Shell Arrays: A New Class of High‐Performance Pseudocapacitive Materials Advanced Materials. ,vol. 23, pp. 2076- 2081 ,(2011) , 10.1002/ADMA.201100058
Xi Wang, Xing-Long Wu, Yu-Guo Guo, Yeteng Zhong, Xinqiang Cao, Ying Ma, Jiannian Yao, Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres Advanced Functional Materials. ,vol. 20, pp. 1680- 1686 ,(2010) , 10.1002/ADFM.200902295
Feng Li, Ding Gao, Xiaomin Zhai, Yanhua Chen, Tao Fu, Dongmin Wu, Zhi-Ping Zhang, Xian-En Zhang, Qiangbin Wang, Tunable, Discrete, Three‐Dimensional Hybrid Nanoarchitectures Angewandte Chemie. ,vol. 50, pp. 4202- 4205 ,(2011) , 10.1002/ANIE.201007433
Yi Zeng, Xi Wang, Hao Wang, Yang Dong, Ying Ma, Jiannian Yao, Multi-shelled titania hollow spheres fabricated by a hard template strategy: enhanced photocatalytic activity. Chemical Communications. ,vol. 46, pp. 4312- 4314 ,(2010) , 10.1039/C0CC00706D
L‐S Zhong, J‐S Hu, H‐P Liang, A‐M Cao, W‐G Song, L‐J Wan, None, Self‐Assembled 3D Flowerlike Iron Oxide Nanostructures and Their Application in Water Treatment Advanced Materials. ,vol. 18, pp. 2426- 2431 ,(2006) , 10.1002/ADMA.200600504
Liang Li, Yue Li, Shuyan Gao, Naoto Koshizaki, Ordered Co3O4 hierarchical nanorod arrays: tunable superhydrophilicity without UV irradiation and transition to superhydrophobicity Journal of Materials Chemistry. ,vol. 19, pp. 8366- 8371 ,(2009) , 10.1039/B914462E
JB Fei, Yue Cui, XH Yan, Wei Qi, Yang Yang, KW Wang, Qiang He, JB Li, Controlled Preparation of MnO2 Hierarchical Hollow Nanostructures and Their Application in Water Treatment Advanced Materials. ,vol. 20, pp. 452- 456 ,(2008) , 10.1002/ADMA.200701231