Generation of ethyl thioxoacetate, a dienophilic thioaldehyde

作者: Christine M. Bladon , Irene E. G. Ferguson , Gordon W. Kirby , Alistair W. Lochead , Duncan C. McDougall

DOI: 10.1039/C39830000423

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摘要: Ethoxycarbonylmethanesulphenyl chloride reacts with triethylamine to give the transient thioaldehyde, ethyl thioxoacetate, which has been trapped, in situ, by cycloaddition various conjugated dienes.

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