The Perturbation of the B1Π and C1Σ+ States in KLi

作者: W Jastrzebski , P Kowalczyk , A Pashov

DOI: 10.1006/JMSP.2001.8389

关键词:

摘要: Abstract Polarization labelling spectroscopy of the B1Π←X1Σ+ and C1Σ+←X1Σ+ band systems in KLi reveals strong mutual perturbation B C states. We show that both excited states can be described a model comprising numerical IPA potentials for unperturbed only 3 parameters to describe their interaction. Our approach allows identify many previously unassigned spectral lines having significant deviation from “regular” positions.

参考文章(24)
Jianyuan Shang, Jianbing Qi, Li Li, A.Marjatta Lyyra, The Perturbation between the G1Πg and 21Δg States of 7Li2 Journal of Molecular Spectroscopy. ,vol. 203, pp. 255- 263 ,(2000) , 10.1006/JMSP.2000.8188
R. Ferber, E. A. Pazyuk, A. V. Stolyarov, A. Zaitsevskii, P. Kowalczyk, Hongmin Chen, He Wang, William C. Stwalley, The c 3Σ+,b 3Π, and a 3Σ+ states of NaK revisited Journal of Chemical Physics. ,vol. 112, pp. 5740- 5750 ,(2000) , 10.1063/1.481149
W. Jastrzȩbski, P. Kowalczyk, 3 (1) Pi u and 3 (1) Sigma u+ states of K2 studied by a polarization-labeling spectroscopy technique. Physical Review A. ,vol. 51, pp. 1046- 1051 ,(1995) , 10.1103/PHYSREVA.51.1046
Robert W. Field, Hélène Lefebvre-Brion, Perturbations in the Spectra of Diatomic Molecules ,(2012)
A. Pashov, W. Jastrzȩbski, P. Kowalczyk, The Li2 F 1Σg+ “shelf” state: Accurate potential energy curve based on the inverted perturbation approach Journal of Chemical Physics. ,vol. 113, pp. 6624- 6628 ,(2000) , 10.1063/1.1311297
Jenning Y. Seto, Robert J. Le Roy, Jean Vergès, Claude Amiot, Direct potential fit analysis of the X 1Σg+ state of Rb2: Nothing else will do! The Journal of Chemical Physics. ,vol. 113, pp. 3067- 3076 ,(2000) , 10.1063/1.1286979
Yasuyuki Kimura, Hélène Lefebvre-Brion, Shunji Kasahara, Hajime Katô, Masaaki Baba, Roland Lefebvre, Interference effects in the predissociation of the Cs2 C 1Πu and (2)3Πu states through the dissociative (2)3Σu+ state Journal of Chemical Physics. ,vol. 113, pp. 8637- 8642 ,(2000) , 10.1063/1.1318737
I. JACKOWSKA, W. JASTRZEBSKI, R. FEBER, O. NIKOLAYEVA, P. KOWALCZYK, Reanalysis of the A 1 Sigma +u state of Na2 by polarization labelling spectroscopy Molecular Physics. ,vol. 89, pp. 1719- 1724 ,(1996) , 10.1080/002689796173039
A. Pashov, I. Jackowska, W. Jastrzȩbski, P. Kowalczyk, POLARIZATION LABELING SPECTROSCOPY OF THE 3 1 AND 6 1SIGMA + STATES IN NAK Physical Review A. ,vol. 58, pp. 1048- 1054 ,(1998) , 10.1103/PHYSREVA.58.1048