Mesoporous graphene paper immobilised sulfur as a flexible electrode for lithium–sulfur batteries

作者: Xiaodan Huang , Bing Sun , Kefei Li , Shuangqiang Chen , Guoxiu Wang

DOI: 10.1039/C3TA12826A

关键词:

摘要: Free-standing flexible mesoporous graphene–sulfur nanocomposite electrodes have been prepared by a sulfur vapor treatment approach. Amorphous homogeneously was distributed in the architectures of porous graphene paper, which immobilized. The as-prepared papers can be directly applied as lithium–sulfur batteries without using binder, conductive additives or an extra current collector. networks effectively facilitate electron transfer and electrolyte diffusion. free-standing sulfur–graphene achieved high discharge capacity 1393 mA h g−1 with enhanced cycling stability good rate performance.

参考文章(40)
H. Hermann, Th. Schubert, W. Gruner, N. Mattern, Structure and chemical reactivity of ball-milled graphite Nanostructured Materials. ,vol. 8, pp. 215- 229 ,(1997) , 10.1016/S0965-9773(97)00010-X
Xiaodan Huang, Kun Qian, Jie Yang, Jun Zhang, Li Li, Chengzhong Yu, Dongyuan Zhao, Functional Nanoporous Graphene Foams with Controlled Pore Sizes Advanced Materials. ,vol. 24, pp. 4419- 4423 ,(2012) , 10.1002/ADMA.201201680
Xiaodan Huang, Liang Zhou, Chengzhong Yu, Dongyuan Zhao, Self-assembly of monodispersed silica nano-spheres with a closed-pore mesostructure Journal of Materials Chemistry. ,vol. 22, pp. 11523- 11528 ,(2012) , 10.1039/C2JM30865G
Guangyuan Zheng, Yuan Yang, Judy J Cha, Seung Sae Hong, Yi Cui, None, Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Nano Letters. ,vol. 11, pp. 4462- 4467 ,(2011) , 10.1021/NL2027684
Fei-fei Zhang, Xin-bo Zhang, Yun-hui Dong, Li-min Wang, Facile and effective synthesis of reduced graphene oxide encapsulated sulfur via oil/water system for high performance lithium sulfur cells Journal of Materials Chemistry. ,vol. 22, pp. 11452- 11454 ,(2012) , 10.1039/C2JM16543K
Xiulei Ji, Kyu Tae Lee, Linda F. Nazar, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Nature Materials. ,vol. 8, pp. 500- 506 ,(2009) , 10.1038/NMAT2460
Mumin Rao, Haimei Zheng, Liang Zhang, Yuanchang Li, Wenhui Duan, Jinghua Guo, Elton J. Cairns, Yuegang Zhang, Liwen Ji, Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells Journal of the American Chemical Society. ,vol. 133, pp. 18522- 18525 ,(2012) , 10.1021/JA206955K
Jia-Zhao Wang, Lin Lu, Mohammad Choucair, John A. Stride, Xun Xu, Hua-Kun Liu, Sulfur-graphene composite for rechargeable lithium batteries Journal of Power Sources. ,vol. 196, pp. 7030- 7034 ,(2011) , 10.1016/J.JPOWSOUR.2010.09.106
Bong Gill Choi, MinHo Yang, Won Hi Hong, Jang Wook Choi, Yun Suk Huh, 3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities ACS Nano. ,vol. 6, pp. 4020- 4028 ,(2012) , 10.1021/NN3003345
Chengdu Liang, Nancy J. Dudney, Jane Y. Howe, Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery Chemistry of Materials. ,vol. 21, pp. 4724- 4730 ,(2009) , 10.1021/CM902050J