Chemical and Electrochemical Behavior of Gallium in the Room-Temperature Ionic Liquid of the Composition [C 6 H 11 N 2 ][N(SO 2 CF 3 ) 2 ]

作者: V. V. Smolenskii , A. L. Bove , A. A. Khokhryakov , A. G. Osipenko

DOI: 10.1023/A:1026220211491

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摘要: The behavior of gallium trichloride in the room-temperature ionic liquid composition [C6H11N2][N(SO2CF3)2] at 298-308 K an inert gas atmosphere was studied by linear and cyclic voltammetry spectrophotometry. reduction oxidation potentials were determined. Assumptions concerning complex species made.

参考文章(8)
Kenneth M. Dieter, Chester J. Dymek, Norman E. Heimer, John W. Rovang, John S. Wilkes, Ionic structure and interactions in 1-methyl-3-ethylimidazolium chloride-aluminum chloride molten salts Journal of the American Chemical Society. ,vol. 110, pp. 2722- 2726 ,(1988) , 10.1021/JA00217A004
S. P. Wicelinski, R. J. Gale, J. S. Wilkes, Low Temperature Chlorogallate Molten Salt Systems Journal of The Electrochemical Society. ,vol. 134, pp. 262- 263 ,(1987) , 10.1149/1.2100425
S. Takahashi, L. A. Curtiss, D. Gosztola, N. Koura, Marie-Louise Saboungi, Molecular Orbital Calculations and Raman Measurements for 1-Ethyl-3-methylimidazolium Chloroaluminates Inorganic Chemistry. ,vol. 34, pp. 2990- 2993 ,(1995) , 10.1021/IC00115A029
Pierre Bonhôte, Ana-Paula Dias, Nicholas Papageorgiou, Kuppuswamy Kalyanasundaram, Michael Grätzel, Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts Inorganic Chemistry. ,vol. 35, pp. 1168- 1178 ,(1996) , 10.1021/IC951325X
Michael K. Carpenter, Mark W. Verbrugge, Electrochemical Codeposition of Gallium and Arsenic from a Room Temperature Chlorogallate Melt Journal of The Electrochemical Society. ,vol. 137, pp. 123- 129 ,(1990) , 10.1149/1.2086346
L. Heerman, R. De Waele, W. D'Olieslager, Electrochemistry and spectroscopy of uranium in basic AlCl3 + N-(n-butyl)pyridinium chloride room temperature molten salts Journal of Electroanalytical Chemistry. ,vol. 193, pp. 289- 294 ,(1985) , 10.1016/0022-0728(85)85071-3