Photocatalytic degradation of pharmaceutical wastes by alginate supported TiO2 nanoparticles in packed bed photo reactor (PBPR)

作者: Santanu Sarkar , Sudip Chakraborty , Chiranjib Bhattacharjee

DOI: 10.1016/J.ECOENV.2015.02.035

关键词:

摘要: In recent years deposal of pharmaceutical wastes has become a major problem globally. Therefore, it is necessary to removes waste from the municipal as well industrial effluents before its discharge. The convectional wastewater and biological treatments are generally failed separate different drugs streams. Thus, heterogeneous photocatalysis process becomes lucrative method for reduction detrimental effects compounds. main disadvantage reuse or recycle tedious job. this work, degradation aqueous solution chlorhexidine digluconate (CHD), an antibiotic drug, by was study using supported TiO2 nanoparticle. concern bring down limitations suspension mode implementation immobilized with help calcium alginate beads. catalyst beads characterized scanning electron microscopy coupled energy dispersive X-ray spectroscopy (SEM/EDAX) characteristic crystalline forms nanoparticle confirmed XRD. efficiency impregnated (TIAB) compared performance free suspension. Although, reduced considerably TIAB but increased quite appreciably. kinetic parameters related work have also been measure. Moreover, susceptibility present system other three ibuprofen (IBP), atenolol (ATL) carbamazepine (CBZ) carried out TiO2. continuous operation in PBPR ensured applicability along treatment. variation residence time significant impact on PBPR.

参考文章(27)
Shipra Mital Gupta, Manoj Tripathi, A review of TiO2 nanoparticles Chinese Science Bulletin. ,vol. 56, pp. 1639- 1657 ,(2011) , 10.1007/S11434-011-4476-1
Thomas A Ternes, Occurrence of drugs in German sewage treatment plants and rivers Water Research. ,vol. 32, pp. 3245- 3260 ,(1998) , 10.1016/S0043-1354(98)00099-2
J Lindsay Oaks, Martin Gilbert, Munir Z Virani, Richard T Watson, Carol U Meteyer, Bruce A Rideout, HL Shivaprasad, Shakeel Ahmed, Muhammad Jamshed Iqbal Chaudhry, Muhammad Arshad, Shahid Mahmood, Ahmad Ali, Aleem Ahmed Khan, None, Diclofenac residues as the cause of vulture population decline in Pakistan Nature. ,vol. 427, pp. 630- 633 ,(2004) , 10.1038/NATURE02317
Ghanem Zayani, Latifa Bousselmi, Farouk Mhenni, Ahmed Ghrabi, None, Solar photocatalytic degradation of commercial textile azo dyes: Performance of pilot plant scale thin film fixed-bed reactor Desalination. ,vol. 246, pp. 344- 352 ,(2009) , 10.1016/J.DESAL.2008.03.059
Diego T. Santos, Boutros F. Sarrouh, Juan D. Rivaldi, Attilio Converti, Silvio S. Silva, Use of sugarcane bagasse as biomaterial for cell immobilization for xylitol production Journal of Food Engineering. ,vol. 86, pp. 542- 548 ,(2008) , 10.1016/J.JFOODENG.2007.11.004
Suja Devipriya, Suguna Yesodharan, None, Photocatalytic degradation of pesticide contaminants in water Solar Energy Materials and Solar Cells. ,vol. 86, pp. 309- 348 ,(2005) , 10.1016/J.SOLMAT.2004.07.013
Ying-Ya Hsu, Tung-Li Hsiung, H. Paul Wang, Yasuhiro Fukushima, Yu-Ling Wei, Juu-En Chang, Photocatalytic degradation of spill oils on TiO2 nanotube thin films Marine Pollution Bulletin. ,vol. 57, pp. 873- 876 ,(2008) , 10.1016/J.MARPOLBUL.2008.03.005
E. Hapeshi, A. Achilleos, M.I. Vasquez, C. Michael, N.P. Xekoukoulotakis, D. Mantzavinos, D. Kassinos, Drugs degrading photocatalytically: Kinetics and mechanisms of ofloxacin and atenolol removal on titania suspensions Water Research. ,vol. 44, pp. 1737- 1746 ,(2010) , 10.1016/J.WATRES.2009.11.044
Maria Klavarioti, Dionissios Mantzavinos, Despo Kassinos, Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environment International. ,vol. 35, pp. 402- 417 ,(2009) , 10.1016/J.ENVINT.2008.07.009
Santanu Sarkar, Ratul Chowdhury, Ranjana Das, Sudip Chakraborty, Heechul Choi, Chiranjib Bhattacharjee, Application of ANFIS model to optimise the photocatalytic degradation of chlorhexidine digluconate RSC Advances. ,vol. 4, pp. 21141- 21150 ,(2014) , 10.1039/C4RA00389F