Toward Less Dependence on Platinum Group Metal Catalysts: The Merits of Utilizing Tin
作者： Richard D. Adams , Douglas A. Blom , Burjor Captain , Robert Raja , John Meurig Thomas
DOI: 10.1021/LA801759D
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摘要: Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these “molecular metallic” entities, supported on mesoporous silica characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 the parent cyclododecatriene (CDT) modest temperatures under solvent-free conditions.
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sci-hub.se 参考文章(31)
Mark S. Holt, William L. Wilson, John H. Nelson, Transition metal-tin chemistry Chemical Reviews. ,vol. 89, pp. 11- 49 ,(1989) , 10.1021/CR00091A002
R.D. Cortright, J.A. Dumesic, Microcalorimetric, Spectroscopic, and Kinetic Studies of Silica Supported Pt and Pt/Sn Catalysts for Isobutane Dehydrogenation Journal of Catalysis. ,vol. 148, pp. 771- 778 ,(1994) , 10.1006/JCAT.1994.1263
Richard D. Adams, Burjor Captain, Jack L. Smith, Michael B. Hall, Chad L. Beddie, Charles Edwin Webster, Superloading of tin ligands into rhodium and iridium carbonyl cluster complexes. Inorganic Chemistry. ,vol. 43, pp. 7576- 7578 ,(2004) , 10.1021/IC0489589
Edmund P. W. Ward, Ilke Arslan, Paul A. Midgley, Andrew Bleloch, John Meurig Thomas, Direct visualisation, by aberration-corrected electron microscopy, of the crystallisation of bimetallic nanoparticle catalysts. Chemical Communications. pp. 5805- 5807 ,(2005) , 10.1039/B511004A
John Meurig Thomas, Richard D. Adams, Erin M. Boswell, Burjor Captain, Henrik Grönbeck, Robert Raja, Synthesis, characterization, electronic structure and catalytic performance of bimetallic and trimetallic nanoparticles containing tin. Faraday Discussions. ,vol. 138, pp. 301- 315 ,(2008) , 10.1039/B706151J
Peter P. Edwards, John Meurig Thomas, Gold in a Metallic Divided State—From Faraday to Present‐Day Nanoscience Angewandte Chemie. ,vol. 46, pp. 5480- 5486 ,(2007) , 10.1002/ANIE.200700428
Carlo Mealli, Thomas B. Rauchfuss, Models for the Hydrogenases Put the Focus Where It Should Be—Hydrogen Angewandte Chemie. ,vol. 46, pp. 8942- 8944 ,(2007) , 10.1002/ANIE.200703413
R.D. Cortright, J.A. Dumesic, L-zeolite-supported platinum and platinum/tin catalysts for isobutane dehydrogenation Applied Catalysis A-general. ,vol. 129, pp. 101- 115 ,(1995) , 10.1016/0926-860X(95)00085-2
J.L. Margitfalvi, A. Tompos, I. Kolosova, J. Valyon, Reaction Induced Selectivity Improvement in the Hydrogenation of Crotonaldehyde over Sn–Pt/SiO2Catalysts Journal of Catalysis. ,vol. 174, pp. 246- 249 ,(1998) , 10.1006/JCAT.1998.1966
Henrik Grönbeck, John Meurig Thomas, Structural and electronic properties of a trimetallic nanoparticle catalyst: Ru5PtSn Chemical Physics Letters. ,vol. 443, pp. 337- 341 ,(2007) , 10.1016/J.CPLETT.2007.06.096