Recent advancement and prospective of heterogeneous carbonaceous catalysts in chemical and enzymatic transformation of biodiesel

作者: Sumit H. Dhawane , Tarkeshwar Kumar , Gopinath Halder

DOI: 10.1016/J.ENCONMAN.2018.04.073

关键词:

摘要: Abstract Carbon derived from waste biomass has emerged as a promising candidate towards the synthesis of catalyst or support for chemical and enzymatic reactions. Excellent surface properties like large specific area high porosity make carbon an exceptional contender support. Moreover, appreciable electron conductivity relative inertness enrich its applicability in processes. The biomass-derived catalysts are environmentally benign reducing footprint cost competitive to other heterogeneous available biodiesel production. Carbons functionalized with different alkali metals, SO3H group, alkoxides, enzymes transition metals enhance catalytic activity transesterification triglycerides alkyl esters. Biodiesel, alternative conventional petro-diesel is studied globally modern era. cost-effective process involves catalysis employing various supports. traditional expensive on indus trial scale; hence, plays vital role minimizing final product due stability, efficient activity, noticeable reusability. For success biorefinery concept present day sustainable development future, there need design new generation multifunctional perhaps consisting biomass. This, turn, will selective transformation non-conventional sources into source energy. Henceforth, review offers broad synopsis evolving carbonaceous such activated carbon, graphene, nanotubes, monoliths nanohorns their use

参考文章(206)
Ma'an Fahmi Rashid Alkhatib, Mutiu K. Amosa, Dzun Noraini Jimat, Mohammed Saedi Jami, Suleyman Aremu Muyibi, Comparative and Optimization Studies of Adsorptive Strengths of Activated Carbons Produced from Steam- and CO2-Activation for BPOME Treatment AENSI Publications. ,(2014)
Daiyu Song, Sai An, Bo Lu, Yihang Guo, Jiyan Leng, Arylsulfonic acid functionalized hollow mesoporous carbon spheres for efficient conversion of levulinic acid or furfuryl alcohol to ethyl levulinate Applied Catalysis B-environmental. ,vol. 179, pp. 445- 457 ,(2015) , 10.1016/J.APCATB.2015.05.047
Ibrahim M Lokman, Umer Rashid, Yun Hin Taufiq-Yap, None, Meso- and macroporous sulfonated starch solid acid catalyst for esterification of palm fatty acid distillate Arabian Journal of Chemistry. ,vol. 9, pp. 179- 189 ,(2016) , 10.1016/J.ARABJC.2015.06.034
Tao Dong, Difeng Gao, Chao Miao, Xiaochen Yu, Charles Degan, Manuel Garcia-Pérez, Barbara Rasco, Shyam S. Sablani, Shulin Chen, Two-step microalgal biodiesel production using acidic catalyst generated from pyrolysis-derived bio-char. Energy Conversion and Management. ,vol. 105, pp. 1389- 1396 ,(2015) , 10.1016/J.ENCONMAN.2015.06.072
Ibrahim M Lokman, Umer Rashid, Yun Hin Taufiq-Yap, None, Production of biodiesel from palm fatty acid distillate using sulfonated-glucose solid acid catalyst: Characterization and optimization Chinese Journal of Chemical Engineering. ,vol. 23, pp. 1857- 1864 ,(2015) , 10.1016/J.CJCHE.2015.07.028
Akash Deep, Amit L. Sharma, Parveen Kumar, Lipase immobilized carbon nanotubes for conversion of Jatropha oil to fatty acid methyl esters Biomass & Bioenergy. ,vol. 81, pp. 83- 87 ,(2015) , 10.1016/J.BIOMBIOE.2015.06.008
Akshay Jain, Rajasekhar Balasubramanian, M.P. Srinivasan, Hydrothermal conversion of biomass waste to activated carbon with high porosity: A review Chemical Engineering Journal. ,vol. 283, pp. 789- 805 ,(2016) , 10.1016/J.CEJ.2015.08.014
Panya Maneechakr, Jittima Samerjit, Siwarak Uppakarnrod, Surachai Karnjanakom, RETRACTED: Experimental design and kinetic study of ultrasonic assisted transesterification of waste cooking oil over sulfonated carbon catalyst derived from cyclodextrin Journal of Industrial and Engineering Chemistry. ,vol. 32, pp. 128- 136 ,(2015) , 10.1016/J.JIEC.2015.08.008