Chemistry of the metal carbonyls : XXVI. Addition of organomanganese pentacarbonyls to fluoro-olefins☆
作者： J.B. Wilford , P.M. Treichel , F.G.A. Stone
DOI: 10.1016/S0022-328X(00)83246-5
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摘要: Abstract At 90–100° methylmanganese pentacarbonyl adds across the double bond of tetra-fluoroethylene to give CH3CF2CF2Mn(CO)5. Under same conditions reactions between phenylmanganese and tetrafluoroethylene, chlorotrifluoroethylene failed desired complexes in reasonable yield. By using ultra-violet irradiation however, it was possible obtain C6H5CF2CF2Mn(CO)5 CH3CF2CFClMn(CO)5 good Reinvestigation addition manganese hydride led formation characterisation two isomers HCFClCF2Mn(CO)5 HCF2CFClMn(CO)5.
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