NMR Evaluation of Receptor Sites in Molecular Sieve Catalysts

作者: E.G. Derouane , J.B. Nagy , B.De Roover , C. Fernandez

DOI: 10.1016/S0167-2991(08)61754-1

关键词:

摘要: Abstract This work shows the correlation between 13 C chemical shifts of tetramethylammonium and tetramethylphosphonium cations exchanged in several zeolites structural parameter W r (s) measuring degree confinement. Thus, an easy-to-apply quantitative tool to gauge at atomic level effective environment active sites molecular sieves has been disclosed.

参考文章(12)
P. Bodart, J.B. Nagy, E.G. Deroijane, Z. Gabellica, A. Gourgue, S. Maroiec, Study of modernite crystallization Applied Catalysis. ,vol. 12, pp. 359- 371 ,(1984) , 10.1016/S0166-9834(00)81673-5
Zelimir Gabelica, Eric G. Derouane, Neils Blom, Synthesis and characterization of pentasil type zeolites: II. Structure-directing effect of the organic base or cation Applied Catalysis. ,vol. 5, pp. 109- 117 ,(1983) , 10.1016/0166-9834(83)80299-1
N. Dewaele, L. Maistriau, J.B. Nagy, Z. Gabelica, E.G. Derouane, Parameters affecting the optimal synthesis of zeolite ZSM-20 Applied Catalysis. ,vol. 37, pp. 273- 290 ,(1988) , 10.1016/S0166-9834(00)80766-6
Eric G. Derouane, Janos B. Nagy, Surface curvature effects on the NMR chemical shift for molecules trapped in microporous solids Chemical Physics Letters. ,vol. 137, pp. 341- 344 ,(1987) , 10.1016/0009-2614(87)80896-5
R. J. Abraham, J. S. E. Holker, 150. An investigation by proton magnetic resonance of the conformation of ring A in some 2-bromo-3-oxo-steroids Journal of The Chemical Society (resumed). pp. 806- 811 ,(1963) , 10.1039/JR9630000806
Shigenobu Hayashi, Kunio Suzuki, Shigemitsu Shin, Kikuko Hayamizu, Osamu Yamamoto, High-resolution solid-state 13C NMR spectra of tetramethylammonium ions trapped in zeolites Chemical Physics Letters. ,vol. 113, pp. 368- 371 ,(1985) , 10.1016/0009-2614(85)80383-3
Eric G. Derouane, Pierre Dejaifve, Zélimir Gabelica, Jacques C. Védrine, Molecular shape selectivity of ZSM-5, modified ZSM-5 and ZSM-11 type zeolites Faraday Discuss. Chem. Soc.. ,vol. 72, pp. 331- 344 ,(1981) , 10.1039/DC9817200331
Eric G. Derouane, Mark E. Davis, On the polarizability of molecular sieves: 129Xe NMR chemical shifts and sorption energetics Journal of Molecular Catalysis. ,vol. 48, pp. 37- 41 ,(1988) , 10.1016/0304-5102(88)85126-5