Stable Modified Electrodes for Use in Amperometric Detectors in Flow Systems

作者: James A. Cox , Thomas J. Gray

DOI: 10.1007/978-1-4899-3704-9_28

关键词:

摘要: Practical analytical applications of modified electrodes, particularly examples that are based on mediated reactions, have been slow to emerge. Only a few attempts, other than our work which is described herein, apply such electrodes flow systems reported. Baldwin and co-workers used an electrode was prepared by mixing cobalt phthalacyanine with carbon paste for the determination hydrazine1 some sulfhydryl compounds2 high performance liquid chromatography amperometric detection. Although results were promising, day-to-day stability without mechanically renewing surface somewhat limited.

参考文章(15)
C.P. Andrieux, J.M. Dumas-Bouchiat, J.M. Savéant, Catalysis of electrochemical reactions at redox polymer electrodes: Kinetic model for stationary voltammetric techniques Journal of Electroanalytical Chemistry. ,vol. 131, pp. 1- 35 ,(1982) , 10.1016/0022-0728(82)87059-9
James A. Cox, Thomas. Gray, Krishnaji R. Kulkarni, Stable modified electrodes for flow injection amperometry: application to the determination of thiocyanate Analytical Chemistry. ,vol. 60, pp. 1710- 1713 ,(1988) , 10.1021/AC00168A015
Joseph. Wang, Lori D. Hutchins, Thin-layer electrochemical detector with a glassy carbon electrode coated with a base-hydrolyzed cellulosic film. Analytical Chemistry. ,vol. 57, pp. 1536- 1541 ,(1985) , 10.1021/AC00285A010
Robert E. Reim, Richard M. Van Effen, Determination of carbohydrates by liquid chromatography with oxidation at a nickel(III) oxide electrode Analytical Chemistry. ,vol. 58, pp. 3203- 3207 ,(1986) , 10.1021/AC00127A062
G Sittampalam, George S Wilson, None, Surface-modified electrochemical detector for liquid chromatography Analytical Chemistry. ,vol. 55, pp. 1608- 1610 ,(1983) , 10.1021/AC00260A039
James A. Cox, Pawel J. Kulesza, Oxidation and determination of nitrite at modified electrodes Journal of Electroanalytical Chemistry. ,vol. 175, pp. 105- 118 ,(1984) , 10.1016/S0022-0728(84)80349-6
Wen-Hong Kao, Theodore Kuwana, Electrochemical oxidation of arsenious acid at a platinum electrode Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 169, pp. 167- 179 ,(1984) , 10.1016/0022-0728(84)80081-9
D.S. Austin, J.A. Polta, T.Z. Polta, A.P.-C. Tang, T.D. Cabelka, D.C. Johnson, Electrocatalysis at platinum electrodes for anodic electoanalysis Journal of Electroanalytical Chemistry. ,vol. 168, pp. 227- 248 ,(1984) , 10.1016/0368-1874(84)87101-4