1-D manganese(ii)-terpyridine coordination polymers as precatalysts for hydrofunctionalisation of carbonyl compounds.
作者： Guoqi Zhang , Haisu Zeng , Sihan Li , Jahvon Johnson , Zixuan Mo
DOI: 10.1039/C9DT04637B
关键词:
摘要: Reductive catalysis with earth-abundant metals is currently of increasing importance and shows potential in replacing precious metal catalysis. In this work, we revealed catalytic hydroboration hydrosilylation ketones aldehydes achieved by a structurally defined manganese(II) coordination polymer (CP) as precatalyst under mild conditions. The manganese-catalysed methodology can be applied to range functionalized turnover numbers (TON) up 990. Preliminary results on the regioselective hydrofunctionalization styrenes Mn-CP catalyst are also presented.
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