Adsorption studies of heavy metal ions on mesoporous aluminosilicate, novel cation exchanger.

作者: H. Sepehrian , S.J. Ahmadi , S. Waqif-Husain , H. Faghihian , H. Alighanbari

DOI: 10.1016/J.JHAZMAT.2009.11.020

关键词:

摘要: Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They characterized by XRD, nitrogen adsorption/desorption measurements, FT-IR thermogravimetry. Adsorption behavior heavy metal ions on this adsorbent studied discussed. The results show that incorporation aluminum in the framework mesoporous MCM-41 has transformed it into an effective cation exchanger. Kd values several increased. Separation Sr(II)–Ce(III), Sr(II)–U(VI) Cd(II)–Ce(III) developed columns novel

参考文章(21)
K.S. Triantafyllidis, V.G. Komvokis, M.C. Papapetrou, I.A. Vasalos, A.A. Lappas, Microporous and mesoporous aluminosilicates as catalysts for the cracking of Fischer-Tropsch waxes towards the production of clean bio-fuels Studies in Surface Science and Catalysis. ,vol. 170, pp. 1344- 1350 ,(2007) , 10.1016/S0167-2991(07)80998-0
Parasuraman Selvam, Suresh K. Bhatia, Chandrashekar G. Sonwane, Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves Industrial & Engineering Chemistry Research. ,vol. 40, pp. 3237- 3261 ,(2001) , 10.1021/IE0010666
Mehran Ghiaci, Reyhaneh Nasr Esfahani, Hamidreza Aghaei, Efficient dehydration of cinnamaldoxime to cinnamonitrile over H3PO4/Al-MCM-41 Catalysis Communications. ,vol. 10, pp. 777- 780 ,(2009) , 10.1016/J.CATCOM.2008.11.036
R.S. Araújo, D.C.S. Azevedo, E. Rodríguez-Castellón, A. Jiménez-López, C.L. Cavalcante, Al and Ti-containing mesoporous molecular sieves: Synthesis, characterization and redox activity in the anthracene oxidation Journal of Molecular Catalysis A-chemical. ,vol. 281, pp. 154- 163 ,(2008) , 10.1016/J.MOLCATA.2007.09.001
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystal templates Journal of the American Chemical Society. ,vol. 114, pp. 10834- 10843 ,(1992) , 10.1021/JA00053A020
Suguru Ito, Hitoshi Yamaguchi, Yoshihiro Kubota, Masatoshi Asami, Mesoporous aluminosilicate-catalyzed allylation of aldehydes with allylsilanes Tetrahedron Letters. ,vol. 50, pp. 2967- 2969 ,(2009) , 10.1016/J.TETLET.2009.04.002
H. Sepehrian, R. Yavari, M. Ghannadi Maragheh, S. Waqif Husain, Sorption of radionuclides on mesoporous Sn(IV) silicate: a new sorbent Radiochimica Acta. ,vol. 96, pp. 105- 109 ,(2008) , 10.1524/RACT.2008.1472
Stephen Brunauer, P. H. Emmett, Edward Teller, Adsorption of Gases in Multimolecular Layers Journal of the American Chemical Society. ,vol. 60, pp. 309- 319 ,(1938) , 10.1021/JA01269A023