Hydrogenation of isobutylene by spiltover hydrogen from Pt/KA-zeolite to NaY-zeolite

作者: S. Ohgoshi , I. Nakamura , Y. wakushima

DOI: 10.1016/S0167-2991(08)63193-6

关键词:

摘要: Abstract We will report that in a hybrid catalyst composed of Pt supported KA-zeolite(Pt/KA) and NaY-zeolite(MaY), isobutylene is hydrogenated by spiltover hydrogen from Pt/KA to NaY. The yields isobutane hydrogenation over Pt/KA, NaY Pt/KA+NaY were 3%, 2% 93%, respectively. These results indicate can not enter the pores be activated on Therefore, we conclude Pt/KA+NaY, spilt Pt/KA.

参考文章(4)
Donald W Breck, Zeolite molecular sieves Krieger. ,(1984)
Stanislas Jean Teichner, Recent studies in hydrogen and oxygen spillover and their impact on catalysis Applied Catalysis. ,vol. 62, pp. 1- 10 ,(1990) , 10.1016/S0166-9834(00)82232-0
Michael Hunger, Jörg Kärger, Harry Pfeifer, Jürgen Caro, Bodo Zibrowius, Martin Bülow, Ryszard Mostowicz, Investigation of internal silanol groups as structural defects in ZSM-5-type zeolites Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 83, pp. 3459- 3468 ,(1987) , 10.1039/F19878303459