Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes.
作者： Friedrich Angersbach-Bludau , Christopher Schulz , Julia Schöffel , Peter Burger
DOI: 10.1039/C4CC03624G
关键词:
摘要: The syntheses and X-ray crystal structures of dinuclear μ-azido μ-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic formal oxidation states metal centers analyzed by theoretical experimental methods, revealing non-innocence PDI nitrido ligands.
rsc.org
sci-hub.se 参考文章(19)
Quinten Knijnenburg, Sandro Gambarotta, Peter H. M. Budzelaar, Ligand-centred reactivity in diiminepyridine complexes. Dalton Transactions. pp. 5442- 5448 ,(2006) , 10.1039/B612251E
Julia Schöffel, Nevena Šušnjar, Stefan Nückel, Daniel Sieh, Peter Burger, 4d vs. 5d - Reactivity and Fate of Terminal Nitrido Complexes of Rhodium and Iridium European Journal of Inorganic Chemistry. ,vol. 2010, pp. 4911- 4915 ,(2010) , 10.1002/EJIC.201000899
Sayuri Matsumura, Kazunori Shikano, Takao Oi, Noriyuki Suzuki, Hirotaka Nagao, Reactions of ruthenium complexes having pyridyl-containing ligands, 2-pyridinecarboxylato and 2,2'-bipyridine, with an azide ion: formation of nitrido-bridged diruthenium complexes. Inorganic Chemistry. ,vol. 47, pp. 9125- 9127 ,(2008) , 10.1021/IC801070A
Claire Newton, Kimberly D. Edwards, Joseph W. Ziller, Nancy M. Doherty, Electron-Rich Nitrido-Bridged Complexes. Structure and Bonding in Triosmium Dinitrido Compounds Inorganic Chemistry. ,vol. 38, pp. 4032- 4037 ,(1999) , 10.1021/IC981257P
Daniel Sieh, Mandy Schlimm, Lars Andernach, Friedrich Angersbach, Stefan Nückel, Julia Schöffel, Nevena Šušnjar, Peter Burger, Metal–Ligand Electron Transfer in 4d and 5d Group 9 Transition Metal Complexes with Pyridine, Diimine Ligands European Journal of Inorganic Chemistry. ,vol. 2012, pp. 444- 462 ,(2012) , 10.1002/EJIC.201101072
Alex J. W. Thom, Eric J. Sundstrom, Martin Head-Gordon, LOBA: a localized orbital bonding analysis to calculate oxidation states, with application to a model water oxidation catalyst Physical Chemistry Chemical Physics. ,vol. 11, pp. 11297- 11304 ,(2009) , 10.1039/B915364K
Markus G. Scheibel, Bjorn Askevold, Frank W. Heinemann, Edward J. Reijerse, Bas de Bruin, Sven Schneider, Closed-shell and open-shell square-planar iridium nitrido complexes Nature Chemistry. ,vol. 4, pp. 552- 558 ,(2012) , 10.1038/NCHEM.1368
Suzanne C. Bart, Krzysztof Chłopek, Eckhard Bill, Marco W. Bouwkamp, Emil Lobkovsky, Frank Neese, Karl Wieghardt, Paul J. Chirik, Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study. Journal of the American Chemical Society. ,vol. 128, pp. 13901- 13912 ,(2006) , 10.1021/JA064557B
Daniel Sieh, Julia Schöffel, Peter Burger, Synthesis of a chloro protected iridium nitrido complex Dalton Transactions. ,vol. 40, pp. 9512- 9524 ,(2011) , 10.1039/C1DT10886G
Maria Ciechanowicz, A. C. Skapski, Structure of a nitrido-bridged ruthenium complex Journal of the Chemical Society D: Chemical Communications. pp. 574- 575 ,(1969) , 10.1039/C29690000574